Polyurethane foams containing brominated diphenyl ether
AssigneeThe General Tire & Rubber Company
InventorDavid S. Cobbledick
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Abstract
Flexible or semiflexible low density polyetherurethane foams containing antimony trioxide, zinc oxide and a brominated diphenyl ether or oxide having from 4 to 10 bromine atoms exhibit good flame retardant properties and also exhibit good resistance to smoldering.
Claims10
In the method of making a flexible or semiflexible low density polyetherurethane foam using the one-shot or prepolymer process by the reaction of (A) a polyetherpolyol having from two to four hydroxyl groups and having a molecular weight of from about 1,000 to 10,000, (B) an organic polyisocyanate and (C) a blowing agent comprising water in admixture with (D) a surfactant, (E) a catalyst, (F) finely divided zinc oxide in an amount of from about 0.1 to 10 parts by weight per 100 parts by weight of said polyol, and (G) finely divided antimony trioxide in an amount of from about 0.5 to 15 parts by weight per 100 parts by weight of said polyol, the improvement comprising incorporating in the formulation prior to foaming a brominated diphenyl ether having from 4 to 10 bromine atoms in an amount of from about 5 to 25 parts by weight per 100 parts by weight of said polyol.
A low density, flexible or semiflexible polyetherurethane foam, the ether moieties of said foam being derived from polyether polyols having a molecular weight of from about 1,000 to 10,000 and having from 2 to 4 hydroxyl groups containing, based on 100 parts by weight of said polyol, (I) finely divided zinc oxide in an amount of from about 0.1 to 10 parts by weight, (II) finely divided antimony trioxide in an amount of from about 0.5 to 15 parts by weight, and (III) from about 5 to 25 parts by weight of a brominated diphenyl ether having from 4 to 10 bromine atoms.
Dependencies are inferred from the claim text.