A method of reducing the melting point of an alkali metal aluminium chloride molten salt electrolyte for an electrochemical cell wherein the alkali metal is selected from the group consisting in lithium and sodium, which comprises doping it with an effective amount of at least one alkali metal fluoride selected from the group consisting in lithium fluoride, sodium fluoride and potassium fluoride, together with sufficient aluminium chloride to maintain the stoichiometric product:
- MAlX.sub.4
- wherein:
- M represents alkali metal cations selected from the group consisting in lithium cations, a mixture of lithium and potassium cations and a mixture of sodium and potassium cations;
- and
- X represents a mixture of chloride and fluoride anions, to reduce the melting point of the doped electrolyte to below 140.degree. C. at atmospheric pressure.