Manufacture of acicular cobalt-containing magnetic iron oxide

A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, aqueous solutions containing cobalt (II) ions and iron (II) ions and aqueous bases to bring the pH of the suspension to not less than 10 are added to this suspension at from 20.degree. to 80.degree. C. under an inert gas blanket, with continued stirring, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an oxidizing atmosphere for from one to three hours at from 110.degree. and 150.degree. C.

A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic material, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, an aqueous solution containing cobalt (II) ions is added to this suspension, followed by the addition of aqueous bases to bring the pH of the suspension to not less than 10, both additions being made at from 20.degree. to 80.degree. C., thereafter an aqueous solution containing iron (II) ions is introduced with continued stirring under an inert gas atmosphere, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an inert gas atmosphere for from two to seven hours at from 130.degree. to 180.degree. C.

A process for the manufacture of acicular magnetic iron oxide which consists of a core of gamma-iron (III) oxide surrounded by a ferrite shell containing, based on the amount of magnetic mateial, from 0.2 to 12% by weight of cobalt (II) ions and from 0.1 to 15% by weight of iron (II) ions, wherein one part by weight of acicular gamma-iron (III) oxide is suspended in not more than four parts by weight of water by vigorous stirring, an aqueous solution containing cobalt (II) ions is added to this suspension, followed by the addition of aqueous bases to bring the pH of the suspension to not less than 10, both additions being made at from 20.degree. to 80.degree. C., thereafter an aqueous solution containing iron (II) ions is introduced with continued stirring under an inert gas atmosphere, and after the cobalt (II) hydroxide and iron (II) hydroxide precipitate has formed under the inert gas atmosphere the entire solid product is filtered off, washed neutral with water and heated in an oxidizing atmosphere for from one to three hours at from 110.degree. to 150.degree. C.