Phthalocyanine reactive dyestuffs, their preparation and their use for dyeing materials containing hydroxyl groups or amide groups
AssigneeBayer Aktiengesellschaft
InventorsVolker Ehrig, Manfred Groll, Klaus Wunderlich
Life of this patent
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Abstract
Dyestuffs of the formula ##STR1## wherein the substituents have the meaning indicated in the description, and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres and for dyeing and printing natural or regenerated cellulose with dyeings and prints which are fast to washing. The dyeings obtained with the dyestuffs are distinguished by good to very good fastness properties, in particular by outstanding fastness to wet processing.
Claims8
Phthalocyanine reactive dyestuffs of the formula ##STR108## wherein Pc the radical of a copper phthalocyanine or nickel phthalocyanine,
- R.sub.1 and R.sub.2 H or optionally substituted alkyl, or R.sub.1 and R.sub.2, together with N, forming a 5-membered or 6-membered heterocyclic ring,
- R.sub.3 and R.sub.4 H or optionally substituted alkyl,
- R.sub.5 and R.sub.6 hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6, together with N, a 5-membered or 6-membered heterocyclic ring,
- B a bridge member selected from the group consisting of ##STR109## a=1 to 3, b=0 to 2,
- c=1 or 2 and
- a+b+c.ltoreq.4.
Phthalocyanine reactive dyestuffs of the formula
- wherein
- Pc the radical of a copper phthalocyanine or nickel phthalocyanine,
- R.sub.1, R.sub.2, R.sub.3 and R.sub.4 hydrogen, methyl or ethyl,
- R.sub.5 and R.sub.6 hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6, together with N, a 5-membered or 6-membered heterocyclic ring,
- B 1,2-phenylene, 1,3-phenylene or 1,4-phenylene optionally substituted by C.sub.1 -C.sub.4 -alkyl groups, C.sub.1 -C.sub.4 -alkoxy groups or halogen atoms,
- a=1-3,
- b=0-2,
- c=1 and
- a+b+c=2-4.
Phthalocyanine reactive dyestuffs of the formula ##STR110## wherein Pc the radical of a copper phthalocyanine or nickel phthalocyanine,
- R.sub.1, R.sub.2, R.sub.3 and R.sub.4 hydrogen, methyl or ethyl,
- R.sub.5 and R.sub.6 hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or
- R.sub.5 and R.sub.6, together with N, a 5-membered or 6-membered heterocyclic ring,
- B 1,2-phenylene, 1,3-phenylene or 1,4-phenylene optionally substituted by C.sub.1 -C.sub.4 -alkyl groups, C.sub.1 -C.sub.4 -alkoxy groups or halogen atoms,
- <
- a<3,
- b>0,
- c=1 and
- a+b+c=3 or 4.
Phthalocyanine reactive dyestuffs of the formula ##STR111## wherein Pc the radical of a copper phthalocyanine or nickel phthalocyanine,
- R.sub.1 -R.sub.4 hydrogen, methyl or ethyl,
- R.sub.5 and R.sub.6 hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6, together with N, a 5-membered or 6-membered heterocyclic ring,
- B 1,2-phenylene, 1,3-phenylene or 1,4-phenylene, optionally substituted by C.sub.1 -C.sub.4 -alkyl groups, C.sub.1 -C.sub.4 -alkoxy groups or halogen atoms,
- a=1 or 2,
- b=0,
- c=1 and
- a+c=2 or 3.
Process for the preparation of phthalocyanine reactive dyestuffs, characterised in that phthalocyanine dyestuffs, containing amino groups, of the formula ##STR112## wherein Pc denotes the radical of a copper phthalocyanine or nickel phthalocyanine,
- R.sub.1 and R.sub.2 denote H or optionally substituted alkyl, or
- R.sub.1 and R.sub.2, together with N, form a 5-membered or 6-membered heterocyclic ring,
- R.sub.3 and R.sub.4 denote H or optionally substituted alkyl,
- B denotes a bridge member selected from the group consisting of ##STR113## a denotes 1 to 3, b denotes 0 to 2,
- c denotes 1 to 2 and
- a+b+c.ltoreq.4,
- are reacted with c mols of a compound of the formula ##STR114## wherein R.sub.5 and R.sub.6 hydrogen, optionally substituted alkyl with 1 to 5 C atoms, optionally substituted cycloalkyl or aralkyl or an optionally substituted aryl radical which is free from sulphonic acid groups and carboxylic acid groups, or R.sub.5 and R.sub.6, together with N, a 5-membered or 6-membered ring.
Dependencies are inferred from the claim text.