Image display device
AssigneeCanon Kabushiki Kaisha
InventorsHiroyuki Imataki, Michiko Takahashi, Masatsune Kobayashi, Tokuya Ohta
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Abstract
An image display device comprises a cell container, at least a pair of electrodes, an electrically responsive electrochromic medium accommodated in said cell container, said electrochromic medium comprising a complexon, Fe.sup.2+ ion and at least one metal ion other than Fe.sup.2+ ion.
Claims13
An image display device which comprises a cell container, at least a pair of electrodes, and an electrically responsive electrochromic medium accomodated in said cell container, said electrochromic medium comprising a complexon, a redox reactive organic substance, Fe.sup.+2 ion and at least one metal ion which is (a) other than a Fe.sup.+2 ion (b) other than an Fe.sup.+3 ion and (c) other than an alkali metal ion, wherein said complexon is a member selected from the group consisting of:
- (1) an aminocarboxylic acid compound containing 1 to 3 aminocarboxylic acid groups represented by the following formula (I) ##STR9## wherein R.sub.1 represents hydrogen, methyl or hydroxyphenyl and n is 1 or 2;
- (2) an aminocarboxylic acid compound containing 1 to 2 aminocarboxylic acid groups represented by formula (I) above and 1 to 2 aminocarboxylic acid groups represented by the following formula (II):
- N--(CR.sub.1 H).sub.n --COOH (II)
- wherein R.sub.1 and n have the same meaning as in formula (I);
- (3) an aminocarboxylic acid compound containing an aminocarboxylic acid group represented by the following formula (III):
- ##STR10## wherein R.sub.1 and n have the same meaning as in formula (I);
- (4) an aminocarboxylic acid compound containing 2 aminocarboxylic acid groups represented by the following formula (IV):
- N--(CR.sub.1 H).sub.n --COOH (IV)
- wherein R.sub.1 and n mean the same as in formula (I);
- (5) an aminocarboxylic acid compound selected from the group consisting of ##STR11## (6) nitrogen, phosphorus and arsenic homologues thereof containing 1 to 2 groups represented by the following formula (V):
- A--(CH.sub.2).sub.n --B
- (V)
- wherein n is 1 or 2, A represents N, P or As and B represents --COOH, ##STR12## with the proviso that B is not --COOH when A is N;
- (7) nitrogen, phosphorus and arsenic homologues thereof containing 1 or 2 groups represented by the following formula (VI):
- ##STR13## wherein n, A and B mean the same as in formula (V);
- (8) nitrogen, phosphorus and arsenic homologues thereof containing 1 group represented by the following formula (VII):
- ##STR14## wherein n, A and B mean the same as in formula (V);
- and (9) mixtures thereof.
Dependencies are inferred from the claim text.