Process for the production of tertiary alcohols
AssigneeToa Nenryo Kogyo Kabushiki Kaisha
InventorsYoshiharu Okumura, Katsumi Kaneko
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Abstract
Tertiary alcohols are produced by the hydration of an isoolefin in the presence as catalyst of an acidic cation exchange resin such as a sulfonated styrene-divinylbenzene copolymer and in the presence of an oxy acid or lactone thereof such as .gamma.-valerolactone. The process is useful for separating isobutylene from a hydrocarbon mixture containing its isomers via preparation of the alcohol, separation from the unreacted hydrocarbons and dehydration of the tertiary butyl alcohol to isobutylene.
Claims10
In a process for the production of tertiary alcohols by causing an isoolefin or a hydrocarbon mixture containing an isoolefin to react with water in the presence of an acidic cation exchange resin, the improvement which comprises carrying out the reaction in the presence of an oxy acid ester selected from the group consisting of glycolic acid methyl ester and glycolic acid ethyl ester.
In a process for the production of tertiary alcohols by causing an isoolefin or a hydrocarbon mixture containing an isoolefin to react with water in the presence of an acidic cation exchange resin, the improvement which comprises carrying out the reaction in the presence of a C.sub.2 to C.sub.5 oxy acid or the lactones, lactides, methyl or ethyl esters thereof, or mixtures thereof.
In a process for the production of tertiary alcohols by causing an isoolefin or a hydrocarbon mixture containing an isoolefin to react with water in the presence of an acidic cation exchange resin, the improvement which comprises carrying out the reaction in the presence of an oxy acid selected from the group consisting of oxyacetic acid, lactic acid, 3-oxypropionic acid, .beta., .beta., .beta.-trichlorolactic acid, oxypivalic acid and .gamma.-oxybutyric acid.
In a process for the production of tertiary alcohols by causing an isoolefin or a hydrocarbon mixture containing an isoolefin to react with water in the presence of an acidic cation exchange resin, the improvement which comprises carrying out the reaction in the presence of a lactone selected from the group consisting of .beta.-propiolactone, .beta.,.beta.-dimethylpropiolactone, .gamma.-butyrolactone, .gamma.-valerolactone and .gamma.-valerolactone.
In a process for the production of tertiary alcohols by causing an isoolefin or a hydrocarbon mixture containing an isoolefin to react with water in the presence of an acidic cation exchange resin, the improvement which comprises carrying out the reaction in the presence of a lactide selected from the group consisting of diglycolide and lactide.
Dependencies are inferred from the claim text.