Method for inhibiting corrosion-causing tendency and coloration of halogen-containing olefin resins with hydrotalcite
AssigneeKyowa Chemical Industry Co., Ltd.
InventorsShigeo Miyata, Masataka Kuroda
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AssigneeKyowa Chemical Industry Co., Ltd.
InventorsShigeo Miyata, Masataka Kuroda
Estimating the term…
In a method for inhibiting the corrosion-causing tendency and coloration of an olefin polymer or copolymer containing a halogen component by incorporating about 0.01 to about 5 parts by weight of a hydrotalcite; the improvement which comprises mixing an olefin polymer or copolymer containing a halogen component attributed to a polymerization catalyst and/or to post-halogenation, with a hydrotalcite of the formula Mg.sub.1-x Al.sub.x (OH).sub.2 A.sub.x/n.sup.n-.mH.sub.2 O wherein 0<x.ltoreq.0.5, m is a positive number, and A.sup.n- represents an anion having a valence of n, or a product resulting from the surface-coating of said hydrotalcite with an anionic surface-active agent, said hydrotalcite having (i) a BET specific surface area of not more than 30 m.sup.2 /g, preferably not more than 20 m.sup.2 /g, (ii) an average secondary particle size of not more than 5 microns, preferably not more than 1.5 microns, and preferably (iii) a crystallite size, in the <003> direction determined by an X-ray diffraction method, of at least 600 A, preferably at least 1000 A.
In a method for inhibiting the corrosion-causing tendency and coloration of an olefin polymer or copolymer selected from the group consisting of polyethylene, polypropylene, poly(1-butene), poly(4-methyl-1-pentene), an ethylene-propylene copolymer and a copolymer of at least one alpha-olefin with a diene, said olefin polymer or copolymer containing a halogen component, by incorporating about 0.01 to about 5 parts by weight of a hydrotalcite in the halogen component-containing olefin polymer or copolymer, the improvement which comprises mixing the olefin polymer or copolymer, containing a halogen component attributed to a polymerization catalyst and/or to post-halogenation, with a hydrotalcite of the formula
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