Back to results
US 4,284,739 AGranted
Block copolymerization process
AssigneeEl Paso Polyolefins Company
InventorEdward A. Zukowski
Life of this patent
Estimating the term…
Abstract
A process for the preparation of ethylene-propylene block copolymers at high catalyst productivity rates resulting in polymer products having improved impact strength-polymerized ethylene content relationship.
Claims11
A continuous sequential vapor phase block copolymerization process for the production of impact resistant ethylene-propylene polymers at high productivity rates, which comprises:
- (A) providing a preformed propylene polymer in finely divided form, said preformed polymer containing active catalyst residues and having been prepared by polymerizing propylene in the presence of a catalyst composition containing the components
- (a) an aluminum trialkyl at least partially complexed with an aromatic acid ester electron donor compound wherein the aluminum trialkyl is one containing from 1 to 8 carbon atoms in the alkyl groups and the molar ratio of trialkyl aluminum to electron donor ranges between 2 and about 5, and
- (b) a complex of a titanium tri- or tetrahalide with an aromatic acid ester electron donor compound supported on magnesium dihalide wherein the titanium content of component (b) is about 1 and about 3 weight percent,
- wherein catalyst components (a) and (b) are provided to the reaction zone in a molar ratio of Al/Ti of between about 10 and about 200;
- (B) introducing said preformed polymer into at least one continuously agitated reaction zone;
- (C) introducing ethylene and propylene monomers to said reaction zone in a molar ratio of ethylene to propylene of from about 0.15 to about 0.3;
- (D) polymerizing said ethylene and propylene monomers in the vapor phase in the reaction zone onto said preformed propylene prepolymer at a temperature of from about 50.degree. F. to about 210.degree. F.
4 more elements
Dependencies are inferred from the claim text.