US 4,284,524 AGranted

Alkaline dishwasher detergent

AssigneeThe Procter & Gamble Company

InventorLawrence A. Gilbert

Life of this patent

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Abstract

Alkaline dishwasher detergent composition having a specific low level of a polyacetal carboxylate for improved hard water filming performance, especially in the presence of precipitating builders. The detergent composition is substantially free of highly alkaline materials and other organic builders.

Claims9

Dependent claims

An automatic dishwashing composition providing optimum cleaning;

spotting and filming;
and physical characteristics consisting essentially of:
(1) from about 20% to about 60% of a detergency builder selected from the group consisting of alkali metal tripolyphosphates, pyrophosphates, orthophosphates, carbonates and mixtures thereof;
(2) from about 10% to about 30% alkali metal silicate solids providing from about 5% to about 15% of SiO.sub.2 ;
(3) a material selected from the group consisting of sodium and potassium dichloroisocyanurates;
dichloroisocyanuric acid;
1,3-dichloro-5,5-dimethylhydantoin;
N,N'-dichlorobenzoylene urea;
paratoluene sulfodichloroamide;
trichloromelamine;
N-chloroammeline;
N-chlorosuccinimide;
N,N'-dichloroazodicarbonamide;
N-chloroacetyl urea;
N,N'-dichlorobiuret;
chlorinated dicyandiamide;
sodium hypochlorite;
calcium hypochlorite;
lithium hypochlorite;
chlorinated trisodium phosphate;
and mixtures thereof;
to provide available chlorine at a level of from about 0.5% to about 3%;
(4) from about 1% to about 9.5% of a low foaming nonionic surfactant;
selected from the group consisting of
(a) the condensation product of 1 mole of a saturated or unsaturated, straight or branched chain alcohol or fatty acid containing from about 10 to about 20 carbon atoms with from about 4 to about 50 moles of ethylene oxide;
(b) polyethylene glycols having molecular weights of from about 1,400 to about 30,000;
(c) the condensation products of 1 mole of alkyl phenol wherein the alkyl chain contains from about 8 to about 18 carbon atoms and from about 4 to about 50 moles of ethylene oxide;
(d) polyoxypropylene, polyoxyethylene condensates having the formula
HO(C.sub.2 H.sub.4 O).sub.x (C.sub.3 H.sub.6 O).sub.y (C.sub.2 H.sub.4 O).sub.x H
where y equals at least 15 and (C.sub.2 H.sub.4 O).sub.x+x equals 20% to 90% of the total weight of the compound and the molecular weight is from about 2,000 to about 10,000;
(e) the compounds of (a) which are capped with propylene oxide, butylene oxide, and/or short chain alcohols, and/or short chain fatty acids;
and
(f) mixtures thereof;
(5) from about 1% to about 30% of a stabilized water-soluble polymer consisting essentially of polyacetal carboxylate segments having the structure ##STR8## wherein M is selected from the group consisting of alkali metal, ammonium tetraalkyl ammonium and alkanol amine groups having from 1 to about 4 carbon atoms in the alkyl and alkanol chains;
n averages at least 4;
and the total number of polyacetal carboxylate segments are at least 50% by weight of the total polymer;
said composition having a pH of from about 9 to 10.9 at 2,500 ppm and being substantially free of materials having a pH of 12 or more at a concentration of 1% in water and other organic chelating builders.

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Dependencies are inferred from the claim text.

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Abstract

An automatic dishwashing composition providing optimum cleaning;

spotting and filming;
and physical characteristics consisting essentially of:
(1) from about 20% to about 60% of a detergency builder selected from the group consisting of alkali metal tripolyphosphates, pyrophosphates, orthophosphates, carbonates and mixtures thereof;
(2) from about 10% to about 30% alkali metal silicate solids providing from about 5% to about 15% of SiO.sub.2 ;
(3) a material selected from the group consisting of sodium and potassium dichloroisocyanurates;
dichloroisocyanuric acid;
1,3-dichloro-5,5-dimethylhydantoin;
N,N'-dichlorobenzoylene urea;
paratoluene sulfodichloroamide;
trichloromelamine;
N-chloroammeline;
N-chlorosuccinimide;
N,N'-dichloroazodicarbonamide;
N-chloroacetyl urea;
N,N'-dichlorobiuret;
chlorinated dicyandiamide;
sodium hypochlorite;
calcium hypochlorite;
lithium hypochlorite;
chlorinated trisodium phosphate;
and mixtures thereof;
to provide available chlorine at a level of from about 0.5% to about 3%;
(4) from about 1% to about 9.5% of a low foaming nonionic surfactant;
selected from the group consisting of
(a) the condensation product of 1 mole of a saturated or unsaturated, straight or branched chain alcohol or fatty acid containing from about 10 to about 20 carbon atoms with from about 4 to about 50 moles of ethylene oxide;
(b) polyethylene glycols having molecular weights of from about 1,400 to about 30,000;
(c) the condensation products of 1 mole of alkyl phenol wherein the alkyl chain contains from about 8 to about 18 carbon atoms and from about 4 to about 50 moles of ethylene oxide;
(d) polyoxypropylene, polyoxyethylene condensates having the formula
HO(C.sub.2 H.sub.4 O).sub.x (C.sub.3 H.sub.6 O).sub.y (C.sub.2 H.sub.4 O).sub.x H
where y equals at least 15 and (C.sub.2 H.sub.4 O).sub.x+x equals 20% to 90% of the total weight of the compound and the molecular weight is from about 2,000 to about 10,000;
(e) the compounds of (a) which are capped with propylene oxide, butylene oxide, and/or short chain alcohols, and/or short chain fatty acids;
and
(f) mixtures thereof;
(5) from about 1% to about 30% of a stabilized water-soluble polymer consisting essentially of polyacetal carboxylate segments having the structure ##STR8## wherein M is selected from the group consisting of alkali metal, ammonium tetraalkyl ammonium and alkanol amine groups having from 1 to about 4 carbon atoms in the alkyl and alkanol chains;
n averages at least 4;
and the total number of polyacetal carboxylate segments are at least 50% by weight of the total polymer;
said composition having a pH of from about 9 to 10.9 at 2,500 ppm and being substantially free of materials having a pH of 12 or more at a concentration of 1% in water and other organic chelating builders.

34 more elements