Control of emissions in FCC regenerator flue gas
AssigneeEngelhard Minerals & Chemicals Corporation
InventorsDavid B. Bartholic, John W. Byrne
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AssigneeEngelhard Minerals & Chemicals Corporation
InventorsDavid B. Bartholic, John W. Byrne
Estimating the term…
A system is described for control of sulfur oxide in emissions to the atmosphere from regenerators of Fluid Catalytic Cracking Units (FCC) in a manner which provides an added controllable variable in heat balanced units. The cracking catalyst used has the capability of reversibly reacting with sulfur oxides in the regenerator flue gas to carry the sulfur back into the reactor where it is converted, at least in part, to hydrogen sulfide which is removed from reaction products in the normal course of treating the cracked products from the reactor. By the disclosed system, regenerator flue gas is cooled and then contacted with hot regenerated catalyst from the regenerator for sorption of sulfur oxides by the catalyst and to cool the catalyst for control of reaction parameters in the FCC reactor.
In a process for catalytic cracking of a sulfur containing hydrocarbon charge by contacting said charge at cracking temperature with a circulating inventory of cracking catalyst which inventory includes a component capable of sorbing oxides of sulfur in an oxidizing atmosphere and of reaction in a reducing atmosphere to release sulfur as hydrogen sulfide whereby the catalyst acquires an inactivating carbonaceous deposit containing sulfur, separating vaporous products of reaction including hydrogen sulfide from circulating catalyst inventory containing said deposit, regenerating the so separated inventory by contact with air at a temperature to burn said carbonaceous deposit thus generating oxides of carbon and sulfur and regenerating the catalyst, separating products of combustion from regenerated catalyst and returning regenerated catalyst to renewed contact with hydrocarbon charge with reduction of sulfur associated with the regenerated catalyst;
Dependencies are inferred from the claim text.