Manufacture of aromatic compounds
AssigneeMobil Oil Corporation
InventorsArthur W. Chester, Yung F. Chu
Life of this patent
Estimating the term…
Abstract
Isomerization of xylenes admixed with other alkyl aromatics of at least eight carbon atoms and with normal or slightly branched paraffins is conducted at 800.degree.-1000.degree. F. with a zeolite like zeolite ZSM-5 of reduced acid activity.
Claims44
A new use of known apparatus for simultaneously isomerizing xylenes and converting ethylbenzene to products readily separable by distillation from the mixture of C.sub.8 aromatics by contacting a mixture of C.sub.8 aromatics with a catalyst at conversion conditions of elevated temperature and under hydrogen pressure in a loop comprising an isomerization reactor for the contact aforesaid, distillation means for separating C.sub.8 aromatics from lower boiling and higher boiling hydrocarbons, means to transfer hydrocarbon effluent of said isomerization reactor to said distillation means, mixing means for mixing fresh feed C.sub.8 aromatics containing xylenes and ethylbenzene with C.sub.8 aromatics separated by said distillation means, a xylene separator for recovery of para xylene, means for transfer of mixed C.sub.8 aromatics from said mixing means to said xylene separator, and means to transfer C.sub.8 aromatics lean in para xylene from said xylene separator to said isomerization reactor, which new use comprises contacting, in the isomerization reactor of said known apparatus, a vapor phase mixture of said C.sub.8 aromatics lean in para xylene together with 5 to 25 weight percent based on total charge to said reactor of paraffin hydrocarbon having 3 to 12 carbon atoms and having no branching in excess of one methyl group on any one carbon atom and fresh charge material containing alkyl benzenes of more than eight carbon atoms with a zeolite catalyst at a temperature of about 800.degree.-1000.degree. F., a pressure of less than 100 pounds per square inch and a weight hourly space velocity between 1 and about 200;
- said zeolite catalyst having a constraint index of 1 to 12, a silica to alumina ratio greater than 12 and a reduced acidity such that less than 2 weight percent of xylene is converted to other compounds when contacted with said catalyst at 900.degree. F., 200 psig and LHSV of 5.
In a process for isomerizing the xylene content of a charge mixture of eight carbon atoms aromatic hydrocarbon compounds which mixture contains xylene, and ethylbenzene by contact at conversion conditions under hydrogen pressure with a catalyst comprising a zeolite having a silica/alumina ratio greater than 12 and a constraint index of 1 to 12, the improvement resulting in conversion of ethylbenzene to benzene and conversion of higher alkyl benzenes to benzene, toluene and xylene which comprises including in the charge mixture 5-25 weight percent based on total charges of paraffin hydrocarbons having 3-12 carbon atoms and having no branching in excess of one methyl group on any carbon atom, maintaining the conversion pressure at more than 100 pounds per square inch and the conversion temperature of about 800.degree. F. to 1000.degree. F. and using such catalyst comprising a zeolite of reduced acid acidity such that less than 2 weight percent of xylene is converted to compounds other than xylene when contacted with said catalyst at 900.degree. F., 200 psig and LHSV of 5.
A process for the manufacture of aromatic hydrocarbons which comprises subjecting a hydrocarbon naphtha to catalytic reforming under conditions to convert naphthenes to aromatic hydrocarbons in a reformate reaction product, distilling said reformate to separate compounds of less than eight carbons from a heavy reformate, mixing said heavy reformate with a recycle stream hereafter defined, contacting the resultant mixture together with hydrogen and 5-25 weight percent based on said mixture of paraffin hydrocarbon having 3-12 carbon atoms and no branching in excess of one methyl group on any carbon atom at pressure above about 100 pounds per square inch and a temperature of about 800.degree.-1000.degree. F. with a zeolite catalyst having a constraint index of 1 to 12, a silica/alumina ratio above about 12 and reduced acidity such that less than 2 weight percent of xylene is converted to compounds other than xylene when contacted with said catalyst at 900.degree. F., 200 psig and LHSV of 5, whereby to isomerize xylene content of said mixture and to convert ethylbenzene and alkylbenzenes of more than eight carbon atoms to benzene, toluene and xylene, distilling the product of said contacting to separate compounds of less than eight carbon atoms and compounds of more than eight carbon atoms from a C.sub.8 fraction, recovering at least one xylene isomer from said C.sub.8 fraction to provide a stream lean in said recovered isomer and mixing said lean stream with said heavy reformate as the recycle stream aforesaid.
In a process for manufacture of a desired xylene isomer which comprises separating the desired xylene isomer from a mixture containing the three xylene isomers, isomerizing the resultant mixture lean in at least one isomer to generate additional amounts of said desired isomer, separating compounds of boiling point higher and lower than xylenes from the isomerization product to provide a recycle stream, mixing said recycle stream with additional aromatic compounds of eight carbon atoms including the three xylene isomers and supplying the resultant mixture to the step aforesaid of separating a desired isomer, the improvement which comprises isomerizing the said mixture lean in a desired isomer in admixture with hydrogen and 5-25 weight percent of paraffin hydrocarbon of 3-12 carbon atoms having no branching in excess of one methyl group on any carbon atom at a temperature of about 800.degree.-1000.degree. F., a pressure above about 100 pounds per square inch and a weight hourly space velocity between 1 and about 200 by contact with a zeolite catalyst having a constraint index of 1 to 12, a silica to alumina ratio greater than 12 and a reduced acidity such that less than 2 weight percent of xylene is converted to other compounds when contacted with said catalyst at 900.degree. F., 200 psig and LHSV of 5.
Dependencies are inferred from the claim text.