Pre-pressuring methanol-cobalt with carbon monoxide in homologation of methanol
AssigneeAllied Chemical Corporation
InventorMiroslav Novotny
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Abstract
An improved process is described for synthetically converting methanol to ethanol in which a mixture of methanol and cobalt catalyst is pre-pressurized with an atmosphere of carbon monoxide at room temperature and at a pressure of about 10 to 1000 psi gauge, in a suitable pressure vessel. A gaseous mixture of carbon monoxide/hydrogen, in the stoichiometric 1:2 molar ratio, is then introduced to react with the methanol/cobalt catalyst mixture and the temperature is raised to about 175.degree. to 240.degree. C. at a pressure of about 3000-6000 psig. The improved process leads to higher selectivities of ethanol formation with lowered amounts of by-products.
Claims4
In a process for converting methanol to ethanol including contacting a mixture of methanol and cobalt catalyst with a gaseous mixture of carbon monoxide and hydrogen gas, in about a 1:2 carbon monoxide/hydrogen molar ratio, respectively, and allowing the combined mixtures to react at a temperature of about 175.degree. C. to 240.degree. C. and a pressure of about 3000-6000 psig., the improvement which comprises pre-pressurizing the methanol-cobalt catalyst mixture with an atmosphere consisting essentially of carbon monoxide in an amount corresponding to a pressure of about 10 to 1,000 psi gauge, at room temperature, or its equivalent at other temperatures, and maintaining said atmosphere of carbon monoxide while introducing said carbon monoxide/hydrogen gaseous mixture.
Dependencies are inferred from the claim text.