Support, catalyst and process for polymerizing olefins
AssigneeThe Dow Chemical Company
InventorRonald L. Gibbs
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Abstract
Olefins are polymerized in the presence of a catalyst which is prepared by the controlled reaction of an aliphatic alcohol such as n-propyl alcohol and a mixture of an alkyl magnesium compound such as n-butyl, sec-butyl magnesium and a silicon tetrahalide such as SiCl.sub.4. After washing the precipitate several times with a hydrocarbon such as hexane, it is suspended in a hydrocarbon such as hexane and a titanium compound such as TiCl.sub.4 is added after which a suitable reducing agent such as diethyl aluminum chloride is added. The thus formed solid catalyst is washed several times with a hydrocarbon solvent such as hexane.
Claims14
A process for the polymerization of one or more alpha olefins under conditions characteristic of Ziegler polymerization which process comprises employing as a polymerization catalyst a composition resulting from the addition of a reducing agent to a mixture of a support suspended in an inert liquid hydrocarbon and a transition metal compound of Groups 4b, 5b, 6b, 7b, or 8 of Mendeleev's Periodic Table under conditions so as to provide a catalytically active solid product and in such proportions that the magnesium:transition metal atomic ratio is from about 0.1:1 to about 30:1 followed by washing the resultant solid catalyst product with an inert liquid hydrocarbon wherein said support comprises the reaction product of (1) a mixture of an organomagnesium compound represented by the formula MgR.sub.2 and a silcon halide represented by the formula R'.sub.4-n SiX.sub.n, said mixture being in a non-polar solvent, with (2) an alcohol represented by the formula R"OH;
- wherein the organomagnesium compound is or can be rendered hydrocarbon soluble and wherein each R, R' and R" is independently a hydrocarbyl group having from 1 to about 20 carbon atoms, X is C1, Br or I, n has a value of from 1 to 4 and wherein the molar ratio of R"OH:MgR.sub.2 is at least 2:1 and the molar ratio of R"OH:R'.sub.4-n SiX.sub.n is sufficient so as to provide at least one X group per OH group.
Dependencies are inferred from the claim text.