PBT Molding compositions containing mica and a composite polymer
AssigneeGAF Corporation
InventorsJohn J. Charles, Robert C. Gasman
Life of this patent
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Abstract
Poly (C.sub.2 -C.sub.4 alkylene terephthalate) molding composition containing mica and a multiphase composite polymer. The multiphase polymer has a first elastomeric phase polymerized from a monomer system including C.sub.1 -C.sub.6 alkyl acrylate as well as crosslinking and graftlinking monomers and has a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase. Preferred compositions also include thermally stable reinforcing fibers such as glass fibers.
Claims20
Polyester molding composition consisting essentially of at least about 40 wt% poly (C.sub.2 -C.sub.4 alkylene terephthalate) with at least about 50 wt% of such poly (C.sub.2 -C.sub.4 alkylene terephthalate) being polybutylene terephthalate having an intrinsic viscosity between about 0.5 and about 2.0 dl/g, such composition containing:
- (a) between about 1 and about 40 wt% based on total molding composition of phlogophite mica flakes having an average particle size between about 40 and 325 mesh with at least 90% of all mica flakes present in the composition having particle sizes between about 40 and about 200 mesh;
- and
- (b) between about 5 and about 30 wt% based on total molding composition of a multiphase composite polymer comprising;
- (1) about 25 to about 95 wt% of a first elastomeric phase polymerized from a monomer system comprising about 75 to 99.8% by weight C.sub.1 to C.sub.6 alkyl acrylate, 0.1 to 5% by weight crosslinking monomer, and 0.1 to 5% by weight graftlinking monomer, said crosslinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups all of which polymerize at substantially the same rate of reaction, and said graftlinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups, at least one of which polymerizes at a substantially different rate of polymerization from at least one other of said reactive groups;
- and
- (2) about 75 to 5 wt% of a final, rigid thermoplastic phase polymerized in the presence of said elastomeric phase.
Dependencies are inferred from the claim text.