Method and system for regenerating fluidizable catalyst particles
AssigneeMobil Oil Corporation
InventorHartley Owen
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AssigneeMobil Oil Corporation
InventorHartley Owen
Estimating the term…
A hydrocarbon conversion-catalyst regeneration operation is described which relies upon an upflowing fluid catalyst mass generally decreasing in density of catalyst particles superimposed by an upflowing more dispersed catalyst phase undergoing catalyst regeneration and combustion of combustible materials to effect elevated temperature regeneration of catalyst deactivated by hydrocarbonaceous material under conditions providing low CO levels in the flue gas and generally less than 0.15 mol percent in the flue gas separated from regenerated catalyst particles. Regenerated catalyst at an elevated temperature of regeneration is mixed with spent catalyst recovered from hydrocarbon conversion in a first contact zone in the presence of a fluidizing gas to obtain an initial mix temperature of at least 1175.degree. F. before contact with a secondary oxygen containing regeneration gas stream in a more dense catalyst phase as a part of the upflowing fluid catalyst mass. The ratio of hot regenerated catalyst to spent catalyst is restricted to obtain a mix temperature particularly promoting the combustion of hydrocarbonaceous material with oxygen containing gas in the upflowing catalyst phases comprising dense and dispersed catalyst phase so as to recover catalyst discharge from said uppermost dispersed catalyst phase at a temperature of at least 1350.degree. F.
In a process for converting hydrocarbons in the presence of fluidized catalyst particles in a hydrocarbon conversion zone and regeneration of the catalyst particles to remove deposited carbonaceous material by burning in a regeneration zone thereby heating the catalyst particles to an elevated temperature suitable for use in hydrocarbon conversion reactions, the improvement which comprises, combining catalyst particles containing deactivating amounts of carbonaceous material with hot freshly regenerated caralyst particles in amounts providing a mix temperature of at least 1175.degree. F., the ratio of regenerated catalyst particles to deactivated catalyst particles in the mix being within the range of 0.5 to 4.0/1, passing the catalyst mix at a temperature of at least 1175.degree. F. suspended in oxygen containing gas under coke burning conditions upwardly through an elongated riser regeneration mixing zone discharging through a mixed catalyst inlet into the lower portion of a relatively dense fluid mass of catalyst being regenerated, introducing additional pre-heated oxygen containing regeneration gas to a bottom portion of said relatively dense fluid mass of catalyst beneath said mixed catalyst inlet in an amount promoting the combustion of carbonaceous deposits and carbon monoxide in said dense fluid mass of catalyst, passing catalyst particles from said relatively dense catalyst mass suspended in oxygen containing combustion gases upwardly through an elongated dispersed catalyst phase contact zone containing less than 8 lbs. per cu. ft. of catalyst, maintaining the ratio of oxygen containing regeneration gas with said suspended catalyst particles in said dispersed catalyst phase sufficient to burn carbon monoxide and raise the temperature of the catalyst to at least 1350.degree. F., and passing high temperature catalyst of at least 1350.degree. F. from said dispersed catalyst phase into a catalyst separation and collection zone, recovering regenerated catalyst from said dispersed phase as a separate dense fluid bed of catalyst and thereafter passing portions of regenerated catalyst directly to a hydrocarbon conversion zone and said riser regeneration mixing zone.
A method of regenerating catalyst particles containing deactivating amounts of carbonaceous material which comprises,
A method for regenerating a crystalline zeolite hydrocarbon conversion catalyst which comprises mixing a crystalline zeolite containing hydrocarbon conversion catalyst deactivated with carbonaceous deposits with sufficient hot regenerated catalyst to provide a mix temperature of at least 1175.degree. F., passing the catalyst mixture thus formed suspended in oxygen containing regeneration gases upwardly under coke burning conditions through a first riser regeneration zone discharging radially into the lower portion of an upwardly flowing more dense fluid bed of catalyst particles, passing additional oxygen containing regeneration gases into the lower portion of said dense fluid bed of catalyst below said radial discharge in an amount sufficient to carry the catalyst as a suspension upwardly as a more dispersed phase of catalyst particles undergoing regeneration into a catalyst separating and collecting zone, raising by combustion the temperature of the catalyst mixture passing through said dense catalyst phase and said dilute catalyst phase to at least 1350.degree. F., and recycling hot regenerated catalyst separated from said dispersed catalyst phase directly to the first riser regeneration zone and to a hydrocarbon conversion zone.
In a process for regenerating a coke deactivated crystalline zeolite hydrocarbon conversion catalyst at a temperature above 1175.degree. F. in an upflowing catalyst suspension comprising a dense phase of catalyst particles superimposed by a more dilute phase of catalyst particles thereabove so as to burn carbon monoxide and recover from said dispersed phase regenerated catalyst at an elevated temperature of at least 1350.degree. F., the improvement which comprises,
In a process for regenerating a coke deactivated crystalline zeolite hydrocarbon conversion catalyst at a temperature about 1175.degree. F. in an upflowing catalyst regeneration operation comprising a relatively large dense phase of catalyst particles in a lower portion of a regeneration zone in open communication with an upwardly flowing dispersed catalyst phase section of substantially smaller diameter, and recovering regenerated catalyst particles from the upper end of said dispersed catalyst phase, the improvement which comprises,
In a process for regenerating a coke deactivated crystalline zeolite hydrocarbon conversion catalyst at an elevated temperature in an upflowing catalyst regeneration zone comprising a relatively large diameter dense fluid bed of catalyst in a lower portion thereof, said regeneration zone diverging into an upwardly extending smaller diameter elongated contact zone wherein coke and carbon monoxide are burned with oxygen containing gas to remove deactivating coke deposits and heat the catalysts to an elevated temperature of at least about 1350.degree. F., the improved method of operation for reducing residual coke on regenerated catalyst below 0.05 weight percent and carbon monoxide in the combustion flue gases less than 0.15 mol percent which comprises,
Dependencies are inferred from the claim text.