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US 4,283,077 AGranted
Indole color former
AssigneeSterling Drug Inc.
InventorsPaul J. Schmidt, William M. Hung
Life of this patent
Estimating the term…
Abstract
Aldehyde or ketone 0-[(3-indolyl)(aryl or heteroaryl)methyl]oximes which are useful as color-formers in pressure-sensitive carbonless duplicating systems and thermal marking systems are prepared by reacting 3-[(arylsulfonyl)(aryl or heteroaryl)methyl]-1H-indoles with aldehyde or ketone oximes in the presence of a base.
Claims3
A pressure-sensitive carbonless duplicating system or thermal marking system containing a support sheet coated with a color-forming substance comprising a compound having the formula ##STR9## wherein:
- R.sub.1 is hydrogen or lower-alkyl;
- R.sub.2 is hydrogen, lower-alkyl or phenyl;
- R.sub.3 and R.sub.4 are independently hydrogen, alkyl containing 1-8 carbon atoms, benzyl, phenyl, phenyl substituted with 1 or 2 halo, lower-alkyl, lower-alkoxy or di-lower-alkylamino groups, or CR.sub.3 R.sub.4 is cyclopentyl, cyclohexyl or cycloheptyl, provided that R.sub.3 and R.sub.4 are not simultaneously hydrogen;
- and
- Z is naphthyl, biphenylyl, phenyl, phenyl substituted with 1 or 2 lower-alkyl, lower-alkoxy, phenyl, halo or nitro groups or Z is a substituent having the formula ##STR10## where in the above formulas R.sub.5 and R.sub.6 are independently lower-alkyl or benzyl;
- R.sub.7 is hydrogen, lower-alkyl, lower-alkoxy, halo or di-lower-alkylamino, and
- R.sub.8 is hydrogen or lower-alkyl.
4 more elements
Dependencies are inferred from the claim text.