Diesel crankcase lubricant composition
AssigneeTexaco Inc.
InventorsBenjamin H. Zoleski, Rodney L. Sung, Gordon R. Schierberg, Gayle P. Hebert
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Abstract
A diesel crankcase lubricant composition containing a non-CO.sub.2 blown 2:1 calcium hydroxide overbased calcium salt of a sulfurized alkylphenolate, an alkenyl succinimide and a pour depressant in a mineral oil base. The composition has excellent silver frictional control without requiring incorporation of a silver friction modifier.
Claims9
A lubricating oil composition characterized by the absence therefrom of a silver friction modifier as well as by improved alkaline retention, silver corrosion protection and percent viscosity increase comprising a hydrocarbon oil of lubricating viscosity containing:
- an alkenyl succinimide detergent-dispersant, a pour depressant and from 0.1 to 90 weight percent of a non-CO.sub.2 blown 2:1 calcium hydroxide overbased calcium sulfurized alkylphenol having an alkylphenol to calcium metal ratio of about 2 to 3 , produced by the steps of:
- (a) overbasing at a temperature between about 350.degree.and 425.degree. F. under a pressure not exceeding 10 psig with from about 1.8 to 2.2 moles of a calcium alkoxyalkoxide of the formula:
- Ca(O--A--OR').sub.2
- where A is alkanediyl of from 1 to 6 carbons and R' is alkyl of from 1 to 25 carbons, a sulfurized calcium alkylphenolate having a calcium content between about 1 and 8.0 weight percent which has the formula:
- ##STR3## wherein R, R' and A are as shown above;
- x ranges from about 1 to 4, y ranges from 0 to 1.0 and z ranges from 0 to 0.1;
- (b) sparging the resulting mixture with an inert gas substantially at the above temperature;
- (c) steaming the sparged mass again at substantially the said temperature;
- (d) repeating said sparging with said gas at an increased stripping rate, continued for about two hours at about 350.degree. F.;
- (e) adding a diluent oil;
- (f) adding a filter aid to the reaction mass, and
- (g) separating a product having the above formula wherein z ranges from 1.8 to 2.2.
The composition of claim l, wherein said pour depressant is a polymethacrylate.
Dependencies are inferred from the claim text.