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US 4,271,006 AGranted
Process for production of carbon artifact precursor
AssigneeExxon Research & Engineering Co.
InventorGhazi Dickakian
Life of this patent
Estimating the term…
Abstract
A process for converting cat cracker bottoms to a feedstock suitable for carbon artifact manufacture, especially carbon fiber manufacture, is provided. Basically, the cat cracker bottom is stripped of fractions boiling below about 400.degree. C., heat soaked and then vacuum stripped to provide a suitable feedstock.
Claims9
A process for preparing a ptich suitable for carbon artifact manufacture comprising:
- providing a cat cracker bottom fraction boiling in the range of from about 200.degree. C. to about 550.degree. C.;
- treating said cat cracker bottom fraction to remove at least a portion of said fraction which boils below about 400.degree. C.;
- heat soaking the so-treated cat cracker bottom in an inert atmosphere at temperatures in the range of about 390.degree. C. to about 450.degree. C. for times ranging from about 1/2 to 10 hours to provide a carbonaceous pitch.
A process for preparing a pitch suitable for carbon fiber production comprising:
- treating a cat cracker bottom which boils in the range of about 200.degree. C. to about 550.degree. C. to remove about 10% to about 90% by weight of the fractions present in said cat cracker bottom which boil below about 400.degree. C.;
- heat soaking the so-treated cat cracker bottom in an inert atmosphere at temperatures in the range of about 390.degree. C. to about 450.degree. C. for time periods ranging from about 1/2 hour to about 10 hours to provide a carbonaceous pitch;
- vacuum stripping said carbonaceous pitch at temperatures in the range of about 320.degree. C. to about 380.degree. C. and at pressures ranging from about 1 to 100 millimeters mercury to removed from about 30% to about 50% by weight of the oil present in said pitch;
- adding an organic fluxing liquid to said vacuum stripped pitch to provide a fluid pitch containing insoluble solids suspended therein, said organic fluxing liquid being employed in the range of about 0.5 to 3 parts by weight of liquid per part of pitch;
- filtering said pitch to separate said solids;
- treating said separated fluid pitch with an organic solvent system having a solubility parameter at 25.degree. C. of between about 8.0 and about 9.5, said treating being at a temperature and with an amount of organic solvent system sufficient to provide a solvent insoluble fraction which is thermally convertible into a deformable pitch containing greater than 75% of an optically anisotropic phase;
- and
- separating said solvent insoluble fraction whereby a pitch suitable for carbon fiber production is obtained.
5 more elements
Dependencies are inferred from the claim text.