Hydrocarbylethyl sulfonyl fluoride
AssigneeChevron Research Company
InventorLouis de Vries
Life of this patent
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Abstract
Hydrocarbylethyl sulfonyl fluorides in which the hydrocarbyl substituent contains at least 3 carbon atoms, can be prepared by reacting 2-mercaptoethanol with chlorine to form chloroethyl sulfonyl chloride which is treated with aqueous potassium fluoride to yield chloroethyl sulfonyl fluoride, followed by treatment with magnesium oxide to yield vinyl sulfonyl fluoride. The vinyl sulfonyl fluoride is adducted to a hydrocarbyl substituent precursor, such as an olefin or halogenated olefin. A representative compound is polyisobutenyl sulfonyl fluoride. The hydrocarbylethyl sulfonamide products for which the hydrocarbylethyl sulfonyl fluorides are intermediates are useful as additives for lubricating oils.
Claims4
Compounds having the formula ##STR16## wherein R.sub.1 is a polymeric 1-olefin-derived hydrocarbyl group of from 50 to 150 carbon atoms with 1 to 3 double bonds.
A process for the preparation of hydrocarbylethyl sulfonyl fluorides of the formula:
- ##STR17## wherein R.sup.1 contains about 3 to 350 carbon atoms consisting essentially of reacting vinyl sulfonyl fluoride with an unsaturated hydrocarbyl precursor selected from the group consisting of;
- an olefin of the formula:
- ##STR18## wherein R.sup.2 is hydrogen, an alkyl group of 1 to 20 carbon atoms, an alkenyl group of 3 to 20 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, or an aryl group of 6 to 12 carbon atoms, R.sup.3 and R.sup.4 are independently hydrogen, an alkyl group of 1 to 20 carbon atoms, an alkenyl group of 3 to 20 carbon atoms or a cycloalkyl group of 5 to 12 carbon atoms, provided that the total number of carbon atoms in R.sup.2, R.sup.3 and R.sup.4 is less than 21, or R.sup.2 may be joined to either of R.sup.3 or R.sup.4 to form a 5 to 12 membered carbocyclic ring;
- an olefin polymer or copolymer, at a temperature of from 100.degree. to 300.degree. C.
Dependencies are inferred from the claim text.