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US 4,268,701 AGranted
Process for producing high octane gasoline and particularly lead-free gasoline
AssigneeInstitut Francais du Petrole
InventorsQuang Dang Vu, Yves Chauvin, Jean Gaillard, Bernard Torck, Michel Hellin
Life of this patent
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Abstract
High octane gasoline is obtained from C.sub.3 /C.sub.4 olefinic cuts by a combination of steps: oligomerization of the C.sub.3 fraction, hydroisomerization of 1-butene in the C.sub.4 cut, fractionation of the resultant C.sub.4 cut, hydrogenation of isobutene and alkylation. Resultant fractions are admixed to produce the desired high octane gasoline.
Claims10
A process for producing a blended high octane gasoline, which comprises the steps of:
- (a) oligomerizing an olefinic C.sub.3 hydrocarbon cut comprising propylene, and recovering an oligomerizate boiling in the gasoline range;
- (b) hydroisomerizing an olefinic C.sub.4 hydrocarbon cut comprising isobutene, isobutane, 1-butene and 2-butene under 1-butene isomerizing conditions, and recovering an isomerized C.sub.4 cut having an increased proportion of 2-butene and a decreased proportion of 1-butene relative to said olefinic C.sub.4 hydrocarbon cut;
- (c) fractionating the isomerized C.sub.4 cut from step (b) and separately recovering a first fraction having an increased proportion of isobutene and isobutane relative to said isomerized C.sub.4 cut, and a second fraction having an increased proportion of 2-butene relative to said isomerized C.sub.4 cut;
- (d) hydrogenating said first fraction from step (c) under isobutene hydrogenating conditions, and recovering an effluent having an increased proportion of isobutane relative to said first fraction;
- (e) admixing the effluent from step (d) and said second fraction from step (c), subjecting the resultant mixture to hydrocarbon alkylation conditions, and recovering an alkylate boiling in the gasoline range;
- and
- (f) blending at least a portion of the oligomerizate from step (a) with at least a portion of the alkylate from step (e) to produce a blended high octane gasoline.
4 more elements
Dependencies are inferred from the claim text.