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US 4,268,667 AGranted
Derivatives of aryl ketones based on 9,10-dihydro-9,10-ethanoanthracene and p-dialkyl-aminoaryl aldehydes as visible sensitizers for photopolymerizable compositions
AssigneeE. I. Du Pont de Nemours and Company
InventorAlbert G. Anderson
Life of this patent
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Abstract
Compositions useful as visible sensitizers for photopolymerizable compositions, the sensitizers being .alpha., .beta.-unsaturated ketones formed by condensing the acetyl or diacetyl derivative of 9,10-dihydro-9,10-ethano(or propano)anthracene with a p-dialkylaminobenzaldehyde; and the photopolymerizable compositions comprising monomer, sensitizer, and initiator, with or without a binder.
Claims12
A composition having the formula ##STR13## wherein:
- ##STR14## R.sup.1 and R.sup.2 are each H, or, R.sup.1 +R.sup.2 is --CH.sub.2 --;
- R.sup.3 is H, or R.sup.3 +R.sup.5 is selected from --CH.sub.2 CH.sub.2 --and --CH.sub.2 CH.sub.2 CH.sub.2 --;
- R.sup.4 is H, or, R.sup.4 +R.sup.6 is selected from --CH.sub.2 CH.sub.2 -- and --CH.sub.2 CH.sub.2 CH.sub.2 --;
- R.sup.5 and R.sup.6 are alkyl groups of 1 to 5 carbon atoms, or together are selected from --Ch.sub.2 ) .sub.4 and --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --;
- R.sup.7 is H or CH.sub.3 ;
- and
- n is 0 or 1, with the proviso that when n is 1, R.sup.1 and R.sup.2 are H.
4 more elements
Dependencies are inferred from the claim text.