Polyvinyl alcohol fiber for binding a fibrous sheet and a process for the preparation thereof
OwnerMasaki Okazaki, Akio Mizobeinventors
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OwnerMasaki Okazaki, Akio Mizobeinventors
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A water-soluble polyvinyl alcohol fiber is obtained by subjecting to the conventional dry or wet spinning process, a solution prepared by adding to a polyvinyl alcohol aqueous solution, an adduct composed of a polyamide condensation product and 1-halogen-2,3-epoxy propane or ethylene glycol diglycidyl ether in the range from 5 to 50 percent by weight based upon the polyvinyl alcohol-after the solution's pH has been adjusted to 2 to 7. The resulting fiber, which has not been subjected to any heat treatment at a temperature above 120.degree. C. is blended with a fibrous material to make a fibrous sheet such as paper or non-woven fabric. By virtue of a subsequent heat-treatment, said polyvinyl alcohol fiber becomes boiling water-resistant; as a result, the wet strength of the fibrous sheet is significantly increased.
A fibrous sheet exhibiting enhanced wet strength comprising a dispersion of paper stock fibers and from 2 to 30 percent by weight of polyvinyl alcohol fibers, said polyvinyl alcohol fiber comprising a water-soluble polyvinyl alcohol fiber containing from 5 to 50 percent by weight of an adduct comprising a polyamide condensation product and a 1-halogen-2,3-epoxy propane or ethylene glycol diglycidyl ether, said fiber, when not having been heat treated at a temperature about 120.degree. C., possesses the latent ability of becoming boiling-water resistant upon being heat treated at a temperature above 120.degree. C., said sheet having been heat treated at a temperature above 120.degree. C.
A process for producing fibrous sheet exhibiting enhanced wet strength comprising forming a slurry of paper stock fibers and from 2 to 30 percent by weight of polyvinyl alcohol fibers, forming
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