Collapsible dispensing tube

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR11## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR12## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR13## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the inside and outside of said metal foil lamination, and, on the outside of both of said polyolefin layers, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR14## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR15## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR16## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, and, on the inside and outside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR17## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR18## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR19## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination and on the outside of said polyolefin layer, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR20## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR21## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR22## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing container having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR23## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR24## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR25## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR26## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR27## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR28## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR29## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR30## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR31## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the inside and outside of said metal foil lamination, and, on the outside of both of said polyolefin layers, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR32## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR33## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR34## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR35## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR36## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR37## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, and, on the inside and outside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR38## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR39## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR40## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR41## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR42## wherein R.sub.1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R.sub.2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR43## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.