Process for oxidation of hydrocarbons
AssigneeHalcon Research and Development Corp.
InventorJames Leacock
Life of this patent
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Abstract
An oxidizable hydrocarbon is oxidized in a reaction zone at elevated temperature in the presence of a liquid reaction medium by introducing the hydrocarbon and a feed stream containing molecular oxygen to the reaction zone under conditions sufficient to oxidize at least a portion of the hydrocarbon; withdrawing at least a portion of the liquid reaction medium from the reaction zone; passing at least a portion of the withdrawn liquid reaction medium to an oxygen injection zone located external to the reaction zone; contacting the liquid in said oxygen-injection zone with a gas stream containing molecular oxygen under conditions sufficient to form a two-phase gas/liquid mixture; and passing said two-phase gas/liquid mixture to the reaction zone as the feed of molecular oxygen thereto.
Claims5
In a process for forming vicinal glycol ester wherein an olefin is oxidized with molecular oxygen in a reaction zone at elevated temperature in the presence of a liquid reaction medium containing a monobasic carboxylic acid and catalyst for the reaction, the improvement which comprises:
- (a) withdrawing at least a portion of the liquid reaction medium containing vicinal glycol ester from the reaction zone;
- (b) passing at least a portion of the withdrawn liquid reaction medium to an oxygen-injection zone external to the reaction zone;
- (c) contacting the liquid in said oxygen-injection zone with a gas stream containing molecular oxygen under conditions sufficient to form a two-phase gas/liquid mixture containing gas bubbles having an average diameter of less than about 0.5 inch distributed throughout the liquid and containing dissolved gases in an amount of less than about 20% of the mass of gases present as said gas bubbles, said two-phase gas/liquid mixture being substantially free of gas bubbles having an effective bubble diameter greater than 8 times said average bubble diameter;
- and
- (d) passing said two-phase gas/liquid to said reaction zone as the feed of molecular oxygen thereto.
Dependencies are inferred from the claim text.