Sizing textile with in situ graft polyester
AssigneeBASF Wyandotte Corporation
InventorRobert B. Login
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Abstract
Graft polyesters which are useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer.
Claims12
A method of sizing a fibrous synthetic organic yarn to facilitate its construction into a fabric comprising the steps of (a) forming a composite of fiber and size by depositing on the yarn about 3 to about 10 percent by weight based upon the dry weight of the yarn of a solventless size mixture comprising a mixture of
- (I). an unsaturated polyester comprising the reaction product of:
- (a) at least one polycarboxylic acid reactant comprising (1) a dicarboxylic acid reactant selected from the group consisting of dicarboxylic acids, corresponding dicarboxylic anhydrides, dicarboxylic acid esters, and their corresponding acyl halides or (2) a mixture of said dicarboxylic acid reactant with up to 20 mole percent of a polycarboxylic acid reactant having a functionality greater than two based upon 100 mole percent of said dicarboxylic acid reactant and
- (b) at least one polyhydric alcohol reactant comprising (1) a diol or (2) a mixture of a diol and up to 20 mole percent of a polyhydric alcohol having a functionality greater than two based upon 100 mole percent of said polyhydric alcohol, wherein a minor effective proportion of said dicarboxylic acid reactant or polyhydric alcohol reactant is alpha, beta-ethylenically unsaturated and
- (II). at least one monovinyl monomer reactant comprising at least one monovinyl monomer having at least one carboxylic group or a mixture of said vinyl monomer with any monofunctional vinyl monomer and (b) heating, irradiating, or both heating and irradiating said mixture in the presence of an initiator.
Dependencies are inferred from the claim text.