Process for dyeing linear polyamides in the melt
AssigneeCiba-Geigy Corporation
InventorsPaul Lienhard, Abul Iqbal, Heinz Peter
Life of this patent
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Abstract
A process for dyeing linear polyamides in the melt, in which process there are used salts from 1:2 chromium complexes of monoazo dyes and amines containing 1-18 C atoms.
Claims12
A process for dyeing linear polyamides in the melt in which the dyeing is effected by means of a dye salt of a 1:2 chromium complex of a monoazo dye and an amine, having the formula ##STR8## wherein A, A' represents identical or different radicals of azo dyes, which radicals are bound to the Cr atom after 2 protons have been split off by the formation of 2 rings,
- X represents a --COO or --SO.sub.3 group not bound to the Cr atom,
- R.sub.1 represents an alkyl or alkylene group having 1-18 C atoms, a cycloalkyl or cycloalkylene group having 5-6 C atoms, or a phenyl or phenylene group, or said group substituted by halogen atoms or by alkyl group having 1-6 C atoms,
- R.sub.3 represents an H atom, an alkyl or alkylene group having 1-18 C atoms, or a cycloalkyl group having 5-6 C atoms,
- R.sub.2, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen, alkyl having 1 to 18 C atoms or cycloalkyl having 5 to 6 C atoms,
- m and t represent the numbers 1-3, r=m-1,
- p and q represent 0 or 1, where if R.sub.3 represents a hydrogen atom, q=0;
- and t=p+q+1.
A linear polyamide containing in the melt a dye salt according to claim 18.
A process for dyeing linear polyamides in the melt in which the dyeing is effected by means of a dye salt of a 1:2 chromium complex of a monoazo dye and an amine, having the formula ##STR14## wherein A, A' represent identical or different radicals of azo dyes, which radicals are bound to the Cr atom after 2 protons have been split off by the formation of 2 rings,
- X represents a --COO or --SO.sub.3 group not bound to the Cr atom,
- R.sub.8 represents a hydrogen atom, or an alkyl group having 1 to 4 C atoms,
- R.sub.9 represents the same as R.sub.8, or a cyclopentyl, cyclohexyl or phenyl group, and
- R.sub.10 represents a straight-chain or branched-chain alkylene group having 1 to 18 C atoms,
- m represents the number 1-3, r=m-1, and n=m/2.
Dependencies are inferred from the claim text.