Preparation of barium-alkoxide salts
AssigneeThe General Tire & Rubber Company
InventorsSundar L. Aggarwal, Ivan G. Hargis, Russell A. Livigni, Hubert J. Fabris
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Abstract
The characteristics of barium t-alkoxide salts used with organolithium compounds as catalyst complexes in the solution polymerization of unsaturated or oxirane monomers to make polymers such as rubbers is improved by reducing or eliminating the nitrogen content of the barium salt and, further, by using a certain mixture of tertiary carbinols and water in forming the barium salt. In certain instances water may be eliminated.
Claims10
The method which comprises polymerizing under inert conditions in a hydrocarbon solvent at a temperature of from about -90.degree. to 100.degree. C. a polymerizable ethylenically unsaturated monomer having an activated double bond with a catalyst in a minor effective amount sufficient to polymerize said monomer to obtain a polymer, said catalyst comprising a complex of
- A. a compound selected from the group consisting of and having the general formula ##STR18## where at least one R is a methyl or cyclohexyl radical and where the remaining Rs are selected from the group consisting of alkyl and cycloalkyl radicals having from 1 to 6 carbon atoms which may be the same or different, and where the mol ratio of a to b is from about 99.5:0.5 to 88:12 and ##STR19## where the Rs are as defined above, where the R's are alkyl radicals of from 2 to 6 carbon atoms which may be the same or different, where the R''s are alkyl radicals of from 1 to 4 carbon atoms which may be same or different and where R'" is a hydrocarbon radical having a molecular weight of from about 250 to 5,000, where the mol ratio of x+y to z is from about 100:0 to 88:12 and where the mol ratio of x to y is from about 1:0.3 to 1:1, said compound A containing not greater than about 0.1% by weight of nitrogen and
- B. a hydrocarbon lithium compound having from 2 to 200 carbon atoms and from 1 to 6 lithium atoms, the mol ratio of A to B based on barium metal and lithium metal being from about 0.60:1 to 1.1:1, said solvent being a solvent for said monomer and polymer.
The method which comprises polymerizing under inert conditions in a hydrocarbon solvent at a temperature of from about -20.degree. to 60.degree. C. a monomer selected from the group consisting of (I) butadiene-1,3 and (II) mixtures of butadiene-1,3 and up to about 30% by weight total of the mixture of styrene and/or isoprene with a catalyst in a minor effective amount sufficient to polymerize said monomer to obtain a polymer and containing a complex of
- A. a compound having the general formula ##STR20## where at least one R is a methyl or cyclohexyl radical, where the remaining Rs are selected from the group consisting of alkyl and cycloalkyl radicals having from 1 to 6 carbon atoms which may be the same or different, where the R's are alkyl radicals of from 2 to 6 carbon atoms which may be the same or different, where the R''s are alkyl radicals of from 1 to 4 carbon atoms which may be the same or different, where R'" is a hydrocarbon radical having a molecular weight of from about 250 to 5,000, where the mol ratio of x+y to z is from about 100:0 to 88:12 and where the mol ratio of x to y is from about 1:0.3 to 1:1, said compound A containing not greater than about 0.1% be weight of nitrogen and
- B. a hydrocarbon lithium compound having from 2 to 200 carbon atoms and 1 to 6 lithium atoms, the mol ratio of A to B based on barium metal and lithium metal being from about 0.60:1 to 1.1:1, said solvent being a solvent for said monomer and said polymer.
Dependencies are inferred from the claim text.