Recovery of acetone produced by carbonylation

A process for the recovery of acetone from the volatile components of the carbonylation reaction mixture produced during the reaction in a carbonylation zone of methyl acetate with carbon monoxide in the presence of a Group VIII noble metal and in the presence of methyl iodide which comprises establishing an acetone to methyl iodide molar ratio of at least 1:10 in the volatile component mixture by supplying acetone, methyl iodide and methyl acetate to the carbonylation zone, fractionally distilling said volatile component mixture to separate as distillate essentially all of said methyl iodide and some of said acetone and methyl acetate, the amount of acetone separated substantially corresponding to the amount supplied to the reaction, distilling the remaining acetone and methyl acetate from the bottoms of said distillation and therefore treating the methyl acetate-acetone mixture to recover acetone therefrom, and recycling to the carbonylation zone the methyl acetate remaining after recovery of acetone from the methyl acetate-acetone mixture.