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US 4,249,011 AGranted
Poly(ethylenically unsaturated alkoxy) heterocyclic compounds
AssigneeMinnesota Mining and Manufacturing Company
InventorLarry A. Wendling
Life of this patent
Estimating the term…
Abstract
Ethylenically unsaturated crosslinking agents and polymerizable monomers are disclosed. These agents contain a heterocyclic nucleus and are capable of forming oxygen insensitive, radiation curable systems.
Claims15
A compound of the formula:
- A.sup.1 --Z--A.sup.2
- wherein A.sup.1 and A.sup.2 are independently groups having terminal ethylenic unsaturation said groups having the formula:
- ##STR19## in which R--O-- is a monovalent residue of an aliphatic terminally unsaturated primary alcohol, ROH, where R is selected from the formulae:
- ##STR20## wherein E is selected from the formulae ##STR21## a and c are independently integers of from 1 to 6, b is zero or an integer of from 1 to 6,
- R.sup.1 and R.sup.4 are independently hydrogen or methyl,
- R.sup.5 is an aliphatic group having 1 to 15 carbon atoms which may be interrupted with up to two groups selected from the class consisting of ether oxygen groups or ##STR22## R.sup.5 having a valence of m+1 wherein m is an integer of 1 to 5, R.sup.2 is selected from the group of hydrogen, ##STR23## wherein R.sup.6 is selected from alkyl and alkenyl groups having up to 5 carbon atoms,
- R.sup.7 is an aliphatic group of up to 8 carbon atoms or aromatic group of up to 8 carbon atoms,
- R.sup.3 is an alkylene group having 1 to 6 carbon atoms and up to one catenary oxygen in the group, and
- Z is a heterocyclic group of the formula:
- ##STR24## wherein X is a divalent group required to complete a 5-membered heterocyclic ring and is selected from the group of ##STR25## wherein R.sup.8 and R.sup.9 are independently selected from hydrogen, alkyl groups of 1 to 4 carbon atoms, cycloalkyl groups of 3 to 6 carbon atoms, and phenyl groups, and
- A.sup.3 is a group having terminal ethylenic unsaturation as defined above for A.sup.1 and A.sup.2.
8 more elements
Dependencies are inferred from the claim text.