Positive-working radiation-sensitive copying composition and method of using to form relief images
AssigneeHoechst Aktiengesellschaft
InventorsJurgen Sander, Gerhard Buhr, Hans Ruckert
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Abstract
This invention relates to a radiation-sensitive copying composition which comprises (a) a compound which forms an acid under the influence of actinic radiation, and (b) an organic polymeric compound which contains recurrent acetal or ketal groupings in its main chain and whose solubility in a liquid developer is increased by the action of an acid, each .alpha.-carbon atom of the alcoholic constituent of the acetal or ketal grouping of the organic polymeric compound being aliphatic. The invention also relates to a process for the production of relief images using a radiation-sensitive copying composition.
Claims14
A positive-working radiation-sensitive copying composition which comprises
- (a) from about 0.1 to 10 percent by weight, based on the weight of the solids of the composition of a compound which forms an acid under the influence of actinic radiation, and
- (b) an organic polymeric compound which contains recurrent units corresponding to the general formula I:
- ##STR7## wherein n--is an integer between 1 and 40,
- R.sub.1 and R.sub.4 are H, alkyl or aryl groups,
- R.sub.3 and R.sub.6 are alkylene oxy groups with at least two carbon atoms, and
- R.sub.2 and R.sub.5 are alkyl or aryl groups, two of the groups R.sub.1, R.sub.2, and R.sub.3, and two of the groups R.sub.4, R.sub.5, and R.sub.6 may be combined to form a substituted or unsubstituted ring,
- or
- R.sub.3 and R.sub.6 are alkylene groups with at least two carbon atoms, and
- R.sub.2 and R.sub.5 are alkoxy group which formed a substituted or unsubstituted ring with R.sub.3 or R.sub.6, and wherein
- R.sub.3 --may be combined with R.sub.4 and R.sub.1 may be combined with R.sub.6 of the neighboring unit to form substituted or unsubstituted rings.
A process for the production of relief images which comprises imagewise exposing a positive-working recording layer, of a radiation-sensitive recording material comprising a support and a recording layer, to actinic radiation to an extent such that the solubility of the layer in an aqueous developer solution is increased, and removing the irradiated portions of the layer by means of an aqueous developer solution,
- said recording layer comprising
- (a) from about 0.1 to 10 percent by weight, based on the weight of the solids of the composition of a compound which forms an acid under the influence of actinic radiation, and
- (b) an organic polymeric compound which contains recurrent units corresponding to the general formula I:
- ##STR12## wherein n--is an integer between 1 and 40,
- R.sub.1 and R.sub.4 are H, alkyl or aryl groups,
- R.sub.3 and R.sub.6 are alkylene oxy groups with at least two carbon atoms, and
- R.sub.2 and R.sub.5 are alkyl or aryl groups, two of the groups R.sub.1, R.sub.2 and R.sub.3 and two of the groups R.sub.4, R.sub.5, and R.sub.6 may be combined to form a substituted or unsubstituted ring,
- R.sub.3 and R.sub.6 --are alkylene groups with at least two carbon atoms, and
- R.sub.2 and R.sub.5 --are alkoxy groups which form a substituted or unsubstituted ring with R.sub.3 or R.sub.6, and wherein
- R.sub.3 --may be combined with R.sub.4 and R.sub.1 may be combined with R.sub.6 of the neighboring unit to form substituted or unsubstituted rings.
Dependencies are inferred from the claim text.