Photopolymerizable composition
AssigneeFuji Photo Film Co., Ltd.
InventorsNobuyuki Kita, Toshio Uchida, Sadaharu Ikeda, Shigeru Sato
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AssigneeFuji Photo Film Co., Ltd.
InventorsNobuyuki Kita, Toshio Uchida, Sadaharu Ikeda, Shigeru Sato
Estimating the term…
A photopolymerizable composition comprising a polymerizable ethylenically unsaturated compound, optionally, a linear organic polymer, and a photopolymerization initiator comprising a combination of a compound represented by the general formula (I) ##STR1## wherein Z represents the non-metal atomic group necessary to form a nitrogen containing heterocyclic nucleus, R.sub.1 represents an alkyl group or a substituted alkyl group, and R.sub.2 represents an alkyl group or an aryl group having a comparatively high photopolymerization initiating ability; and a compound represented by the general formula (II) ##STR2## wherein X represents a halogen atom, Y represents --CX.sub.3, --NH.sub.2, --NHR.sup.1, --NR.sup.1.sub.2 or OR.sup.1, R.sup.1 represents an alkyl group or an aryl group and R represents an alkyl group, an alkyl group substituted with at least one chlorine atom, an aryl group, a substituted aryl group or a substituted alkenyl group.
In a photopolymerizable composition comprising a monomer having at lest two ethylenically unsaturated bonds which is capable of photopolymerization upon exposure to actinic radiation, a photopolymerization initiator and, optionally, a linear organic polymer, the improvement which comprises said photopolymerization initiator comprising a combination of at least one compound represented by the formula (I) ##STR40## wherein Z represents the non-metal atoms necessary to form a nitrogen containing heterocyclic nucleus, R.sub.1 represents an alkyl group or a substituted alkyl group, and R.sub.2 represents an alkyl group or an aryl group, and at least one compound represented by the formula (II) ##STR41## wherein X represents a halogen atom, Y represents --CH.sub.3, --NH.sub.2, --NHR', --NR'.sub.2 or --OR' wherein R' represents an alkyl group or an aryl group, and R represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or a substituted alkenyl group and wherein said photopolymerization initiator is present in an amount of 1 to 10% by weight based on the total weight of the polymerizable ethylenically unsaturated compound and the linear organic high molecular weight compounds and wherein the ratio of the compound represented by formula (I) to the compound represented by formula (II) of said photopolymerization initiator is 4:1 to 1:4.
Dependencies are inferred from the claim text.