A process for separating and recovering concentrated hydrochloric acid from the crude product produced from the acid hydrolysis of a cellulose-containing material, the crude product comprising concentrated hydrochloric acid and the sugars produced from the acid hydrolysis of the cellulose-containing material, into a first fraction comprising the concentrated hydrochloric acid and a second fraction comprising the sugars, the process comprising:
- (1) contacting the crude product with an organic solvent consisting essentially of at least one C.sub.5 -C.sub.9 alcohol such that the organic solvent is enriched with the concentrated hydrochloric acid,
- (2) separating the enriched organic solvent from the concentrated hydrochloric acid depleted crude product, and
- (3) recovering the concentrated hydrochloric acid from the enriched organic solvent.