Method of handling radioactive alkali metal waste
AssigneeThe United States of America as represented by the United States Department of Energy
InventorsRaymond D. Wolson, Charles C. McPheeters
Life of this patent
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Abstract
Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.
Claims13
A method of treating radioactive aklali metals or radioactive solid salts thereof, said method comprising mixing particulate silica substrate material having a particle size such that the majority of the substrate material passes through a 200 mesh sieve and the radioactive material in a rotary drum calciner and converting the radioactive material to alkali metal monoxide by reaction with oxygen present in a diluent at a temperature sufficient to initiate the reaction thereby forming particulate substrate particles coated with alkali metal monoxide, said reaction temperature being controlled by the amount of oxygen present in the diluent to ensure the reaction product remains flowable for easy handling.
A method of treating radioactive sodium or potassium metals or radioactive solid salts thereof, said method comprising mixing silica particles most of which are of a size to pass through a 95 mesh screen and the radioactive material, and oxidizing the radioactive material to the monoxide in a rotary drum calciner by passing oxygen in a diluent over the mixture to form particulate silica coated with sodium monoxide or potassium monoxide or mixtures thereof, the reaction temperature being controlled by the amount of oxygen present in the diluent and being maintained at about 250.degree. C. or less.
A method of storing radioactive waste as glass, comprising providing radioactive alkali metals or solid salts thereof, mixing particulate silica having a particle size the majority of which passes through a 200 mesh screen with the radioactive material, oxidizing the radioactive material in a rotary drum calciner at a temperature less than about 200.degree. C. by passing oxygen in a heavier than air diluent over the mixture to form particulate silica coated with alkali metal monoxide which is easily flowable and fusing said alkali metal monoxide coated silica to form glass.
Dependencies are inferred from the claim text.