Molten salt synthesis of barium and/or strontium titanate powder

A process for producing alkaline earth titanate powder which consists essentially of providing particulate TiO.sub.2 in at least stoichiometric amount or particulate precursor therefor, providing particulate alkaline earth oxide in at least stoichiometric amount or particulate precursor therefor, said alkaline earth oxide being selected from the group consisting of BaO, SrO, and mixtures thereof, providing an alkali chloride salt selected from the group consisting of sodium chloride, potassium chloride and mixtures thereof, forming a mixture of said TiO.sub.2 or precursor therefor, said alkaline earth oxide or precursor therefor and said chloride salt solvent, said chloride salt being used in an amount of at least about 20% by weight of the total amount of said TiO.sub.2, alkaline earth oxide and said chloride salt, heating said mixture to a reaction temperature at least sufficient to melt said chloride salt, each said precursor decomposing completely at or below said reaction temperature to form said oxide and by-product gas, said chloride salt in molten form being a solvent for said TiO.sub.2 and alkaline earth oxide, maintaining said reaction temperature dissolving and reacting said TiO.sub.2 and alkaline earth oxide in said molten salt and precipitating said alkaline earth titanate, and recovering said precipitated alkaline earth titanate by dissolving said chloride salt and separating said precipitated alkaline earth titanate from the resulting salt solution.