Lubricant compositions containing dispersant additives
AssigneeChevron Research Company
InventorsRobert A. Lewis, Lewis R. Honnen
Life of this patent
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Abstract
Lubricant compositions for internal combustion engines are provided containing dispersant additives which prevent sludge and varnish formation in the crankcase. The additives are oil-soluble poly(oxyalkylene) aminocarbamates comprising a hydrocarbyl-terminated poly(oxyalkylene) chain of 2-5 carbon oxyalkylene units.
Claims24
A lubricating oil composition comprising a major amount of an oil of lubricating viscosity, and a minor amount of a hydrocarbylpoly(oxyalkylene) aminocarbamate of molecular weight from about 600 to 10,000, and having at least one basic nitrogen atom;
- wherein said poly(oxyalkylene) moiety is composed of oxyalkylene units selected from 2 to 5 carbon oxyalkylene units of which at least a sufficient number are branched chain oxyalkylene units to render said carbamate soluble in said composition;
- and said hydrocarbyl group contains from 1 to about 30 carbon atoms.
A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and a minor amount of a compound of the formula:
- ##STR5## wherein two R.sup.3 groups attached to the same nitrogen atom and taken together with said nitrogen atom may form a 5 or 6 membered saturated or unsaturated nitrogen heterocyclic radical;
- wherein said heterocyclic radical may be substituted with substituents selected from:
- (A) hydrogen, (B) hydrocarbyl groups of from 1 to 10 carbon atoms;
- (C) acyl groups of from 2 to 10 carbon atoms;
- and (D) monoketo, monohydroxy, mononitro, monocyano, lower alkyl and lower alkoxy derivatives of the substituents of (B) and (C);
- wherein the remaining R.sup.3 groups are the same or different substituents selected from (A), (B), (C), (D) and poly(oxyalkylene) oxycarbonyl groups of the formula R--OC.sub.g H.sub.2g).sub.m O--C(O)-- in which g is an integer from 2 to 5;
- j is an integer such that the molecular weight of the poly(oxyalkylene) group is about 500 to 5,000, and R is a hydrocarbyl group of from 1 to 30 carbon atoms, wherein the R.sup.1 are the same or different alkylene, carbonyl, oxycarbonyl, or hydroxy-substituted alkylene radical of from 2 to 6 carbon atoms, and R.sup.2 is carbonyl, alkylene carbonyl or alkylene of 2 to 4 carbon atoms with vicinal linkages;
- wherein at least one of the R.sup.3 groups is said poly(oxyalkylene) oxycarbonyl group in which a sufficient number of oxyalkylene units, --OC.sub.g H.sub.2g --, are branched chains C.sub.3 -C.sub.5 oxyalkylene units to render said compound soluble in said lubricating oil composition;
- wherein R.sup.3, R.sup.1, and R.sup.2 are selected such that at least one nitrogen atom is a basic nitrogen atom;
- and wherein a is 0 or 1, b is an integer 0 to 4, c is 0 or 1, d is 0 or 1, e is 0 or 1, f is 0 or 1 and equal to 1 when c is 0, and the sum f+b+2c+e is equal to or greater than 2.
Dependencies are inferred from the claim text.