Novel glycylmethylphosphinic acid derivatives, process for their production and use thereof
AssigneeCiba-Geigy Corporation
InventorLudwig Maier
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AssigneeCiba-Geigy Corporation
InventorLudwig Maier
Estimating the term…
The present invention relates to novel herbicidally active and plant growth-regulating glycylmethylphosphinic acid derivatives of the formula ##STR1## wherein R represents hydrogen, --CH.sub.2 COOH or an easily removable radical (e.g. benzyl, tert-butyl), R' represents a --OH or --OR.sub.1 group, in which R.sub.1 is a cation, a lower aliphatic radical, cycloalkyl or NH.sub.2, R" represents hydrogen, a cation or lower alkyl and R'" represents optionally substituted alkyl or phenyl. These compounds are obtained by reacting a N-substituted glycine HOOC--CH.sub.2 --NH--R with formaldehyde and a phosphonous acid ##STR2## in a strongly acid solution and optionally removing the radical R by catalytic hydrogenation or with HBr. The compounds of the formula I are used as active ingredients of compositions especially for the post-emergent control of weeds or for inhibiting plant growth.
A glycylmethylphosphinic acid derivative of the formula I ##STR33## wherein R represents hydrogen, a C.sub.1 -C.sub.6 alkyl radical, benzyl, diphenylmethyl or triphenylmethyl, or the group HOOC--CH.sub.2 --,
Dependencies are inferred from the claim text.