Process for homogeneous hydrogenation of esters
AssigneeAllied Chemical Corporation
InventorsRoger A. Grey, Guido P. Pez
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Abstract
A novel process is described for the homogeneous hydrogenation of carboxylic acid esters to primary alcohols utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted in solution under mild conditions of temperature and pressure with high selectivity and eliminates the disadvantages of utilizing heterogeneous catalysts. A process is also described for decarbonylating formate esters utilizing said compositions as catalysts.
Claims8
A process for hydrogenating an ester selected from the group consisting of methyl acetate, ethyl acetate, methyl propionate, methyl trifluoroacetate, trifluoroethyl triflouroacetate and dimethyl oxalate, comprising contacting a solution of hydrogenation catalyst and said ester, neat or in an inert solvent therefor, with an atmosphere containing hydrogen gas, at a temperature of about 0.degree. to 150.degree. C., under a pressure of about 0 to 150 psig (101 to 1135 kPa absolute) of gaseous hydrogen, said catalyst being of the group consisting of potassium tris (triphenylphosphine) ruthenium hydride, potassium triphenylphosphine diphenylphosphide ruthenium hydride, potassium tris (triphenylphosphite) ruthenium hydride, potassium tris triphenylphosphine rhodium hydride, and potassium tris (methyldiphenylphosphine) ruthenium hydride.
Dependencies are inferred from the claim text.