A thermally stable polymer concrete composition comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer containing pendant groups selected from the group consisting of CH.sub.3, CH.dbd.CH.sub.2, C.sub.2 H.sub.5, C.sub.6 H.sub.5, and mixtures thereof, and capable of being crosslinked, and at least one olefinically unsaturated crosslinking monomer in an amount of about 15% to 50% by weight of said monomer mixture, and about 70-90% by weight of an inorganic filler system containing silica sand and portland cement in ratios ranging from about 9 parts sand to 1 part cement, to, 7 parts sand to 3 parts cement.