Polyoxymethylene molding composition containing melamine formaldehyde polycondensate
AssigneeDeutsche Gold -und Silber-Scheidearstalt vormals Roessler
InventorsHerbert Amann, Gerhard Morlock
Life of this patent
Estimating the term…
Abstract
In a molding composition comprising a polyoxymethylene, a melamine formaldehyde polycondensate and an antioxidation agent, the improvement wherein said melamine formaldehyde polycondensate is a finely divided, cross-linked, substantially water insoluble polycondensate comprising the precipitation product obtained by reacting formaldehyde and melamine in a molar ratio between 1.2:1 and 10.0:1, and wherein said polycondensate is in an amount of about 0.001 to about 30 percent by weight, related to the total weight of said composition.
Claims26
In a molding composition comprising a polyoxymethylene, a melamine formaldehyde polycondensate as thermal stabilizer and an antioxidation agent, the improvement wherein said melamine formaldehyde polycondensate is a finely divided, cross-linked substantially water insoluble polycondensate comprising the precipitation product obtained by reacting formaldehyde, melamine and at least one other substance that can react to form a part of said polycondensate wherein the molar ratio of formaldehyde to melamine plus said other substance is between 1.2:1 and 10.0:1;
- up to 20 mole percent of said melamine being replaced with said at least one other substance that can react to form a part of said polycondensate;
- and said polycondensate is in an amount of about 0.001 to about 30 percent by weight, related to the total weight of said composition, said polyoxymethylene has a crystallite melting point of about 140.degree. C. to about 180.degree. C., a density of about 1.38 to about 1.45 g/ml (DIN 53 479), and a viscosity of at least about 30 ml/g when measured at 135.degree. C. with a solution of 0.5 g polyoxymethylene in 100 ml dimethylformamide containing 2% by weight diphenylamine;
- said polycondensate has a primary particle size less than about 1 .mu.m, and a specific surface up to about 250 m.sup.2 /g.
In a molding composition comprising a polyoxymethylene, a melamine formaldehyde polycondensate and an antioxidation agent, the improvement wherein said melamine formaldehyde polycondensate is a cross-linked, substantially water insoluble polycondensate having a particle size of less than about 10 .mu.m, said polycondensate comprising the precipitation product obtained by reacting formaldehyde, melamine and at least one other substance that can react to form a part of said polycondensate wherein the molar ratio of formaldehyde to melamine plus said other substance is between 1.2:1 and 10.0:1;
- up to 20 mole percent of said melamine being replaced with said at least one other substance that can react to form a part of said poly condensate and said polycondensate is in an amount of about 0.001 to about 30% by weight related to the total weight of said composition.
Dependencies are inferred from the claim text.