Preparation of 1-azolyl-3,3-dimethyl-1-phenoxy-butan-2-ones
AssigneeBayer Aktiengesellschaft
InventorsHermann Arold, Hans-Ludwig Elbe, Eckart Kranz, Wolfgang Kramer, Jorg Stetter, Claus Stolzer, Rudolf Thomas
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AssigneeBayer Aktiengesellschaft
InventorsHermann Arold, Hans-Ludwig Elbe, Eckart Kranz, Wolfgang Kramer, Jorg Stetter, Claus Stolzer, Rudolf Thomas
Estimating the term…
In the reaction of 1-chloro-3,3-dimethylbutan-2-one with a phenol to form an ether-ketone, halogenating it to form a halogenoether-ketone and reacting it with imidazole or 1,2,4-triazole to form a 1-azolyl-3,3-dimethyl-1-phenoxybutan-2-one of the formula ##STR1## in which X is N or CH, n is an integer from 0 to 4, and Y each independently is halogen, phenyl, phenoxy, nitro, alkyl, alkoxy or cycloalkyl, the improvement which comprises effecting all steps successively in an aromatic hydrocarbon or chlorinated aliphatic or aromatic hydrocarbon as solvent without intermediate isolation. The products are obtained in high yield.
A process for the preparation of a 1-azolyl-3,3-dimethyl-1-phenoxy-butan-2-one of the formula ##STR24## in which X is N or CH,
Dependencies are inferred from the claim text.