Copolyamide resins from piperazine and polyoxyalkylene diamine having improved creep resistance
AssigneeEmery Industries, Inc.
InventorHubert J. Sharkey
Life of this patent
Estimating the term…
Abstract
Copolyamides derived from a mixture of short-chain and long-chain saturated aliphatic dicarboxylic acids, piperazine and a polyoxyalkylene diamine are excellent hot melt adhesives useful with a variety of substrates. These thermoplastic copolyamide resins are particularly useful adhesives for vinyl materials and are resistant to creep.
Claims9
A thermoplastic copolyamide adhesive resin having improved creep resistance consisting essentially of the polymeric reaction product of essentially stoichiometric amounts of:
- (a) a mixture of saturated aliphatic dicarboxylic acids containing a short-chain dicarboxylic acid having from 2 to 7 carbon atoms and a long-chain dicarboxylic acid having from 8 to 14 carbon atoms;
- (b) piperazine;
- and
- (c) a polyoxyalkylene diamine of the general formula ##STR2## where R is hydrogen or a methyl group and m is a positive integer such that the average molecular weight of the polyoxyalkylene diamine is between about 200 and 800;
- the equivalents ratio of the long- to short-chain dicarboxylic acids ranging from 0.5:0.5 to 0.9:0.1 and the equivalents ratio of the piperazine to polyoxyalkylene diamine ranging from 0.7:0.3 to 0.95:0.05.
A thermoplastic copolyamide adhesive resin having improved creep resistance consisting essentially of the polymeric reaction product of essentially stoichiometric amounts of
- a mixture of saturated aliphatic dicarboxylic acids containing a long-chain dicarboxylic acid having from 8 to 14 carbon atoms and a short-chain dicarboxylic acid having from 2 to 7 carbon atoms, the equivalents ratio of long- to short-chain dicarboxylic acids ranging from 0.5:0.5 to 0.9:0.1, and
- a mixture of piperazine and a polyoxyalkylene diamine of the formula ##STR3## where R is hydrogen or a methyl group and m is a positive integer such that the average molecular weight of the polyoxyalkylene diamine is between about 200 and 800, the equivalents ratio of piperazine to polyoxyalkylene diamine ranging from 0.7:0.3 to 0.95:0.05, and containing an amount up to 20 percent, based on the total amine equivalents, of an aliphatic, cycloaliphatic or aromatic amine having 2 to 10 carbon atoms, a dipiperidyl type diamine selected from the group consisting of 1,2-di(4-piperidyl)ethane, 1,3-di(4-piperidyl)propane and 1,4-di(4-piperidyl)butane or an N-substituted piperazine or dipiperidyl type diamine wherein the substituent is an aminoalkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms.
Dependencies are inferred from the claim text.