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US 4,228,281 AGranted
Dicarboxylic acids containing triazine rings
AssigneeCiba-Geigy Corporation
InventorsThomas Kainmuller, Jurgen Habermeier, Lothar Buxbaum
Life of this patent
Estimating the term…
Abstract
Dicarboxylic acids containing at least two triazine rings are very suitable for producing thermoplastic polyesters having high glass transition temperatures and high dimensional stability under heat, and at the same time good processing characteristics.
Claims15
A compound of the formula ##STR17## in which n has a value from 1 to 100,
- R.sup.1, R.sup.2, R.sup.3 and R.sup.5 independently of one another are each a hydrogen atom, a straight- or branched-chain alkyl of 1 to 22 C atoms, cycloalkyl of 5 to 7 C atoms, cyclohexylmethyl, aryl of 6 to 10 C atoms, benzyl, or said cycloalkyl, said cyclohexylmethyl, said aryl or said benzyl substituted with alkyl of 1 to 4 C atoms, or
- R.sup.1 and R.sup.2 together are alkylene of 3 to 7 C atoms, 3-oxapentylene or 3-thiapentylene,
- R.sup.4 is a straight- or branched-chain alkylene of 2 to 18 C atoms, cycloalkylene of 5 to 7 C atoms, arylene of 6 to 10 C atoms, cycloalkylenealkylene or cycloalkylenebisalkylene with 1 to 4 C atoms in the alkylene group, arylenealkylene or arylenebisalkylene with 1 to 4 C atoms in the alkylene group;
- or said cycloalkylene, said cycloalkylenealkylene or said cycloalkylenebisalkylene substituted with alkyl of 1 to 4 C atoms, or said arylene, said arylenealkylene or said arylenebisalkylene substituted by alkyl of 1 to 6 C atoms or by halogen, or
- R.sup.4 is phenylene-X-phenylene where X is a direct bond, O, S, SO.sub.2, alkylene of 1 to 3 C atoms, alkylidene of 2 to 12 C atoms, cycloalkylidene of 5 to 6 C atoms, benzylidene, bisphenylmethylidene, 1,1,1-trichloroethylidene or -O-p-phenylene-O--, or
- R.sup.4 together with one R.sup.3 and the N atom to which they are bound form a ring having 4 to 7 C atoms, or R.sup.4, and also both R.sup.3 s together, are alkylene groups having 1 to 5 atoms, and forming together with the two N atoms a 5- to 7-membered ring, and
- R.sup.6 is a straight- or branched-chain alkylene or alkylidene of 1 to 12 C atoms, o-phenylene, m-phenylene, p-phenylene, p-benzylene or p-cyclohexylene or
- the corresponding acid halides, or the corresponding esters where the ester moiety is alkyl or hydroxyalkyl of 1 to 12 C atoms, cycloalkyl or hydroxycycloalkyl of 5 to 6 ring carbon atoms or aryl of 6 to 10 C atoms.
5 more elements
Dependencies are inferred from the claim text.