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AssigneeAllied Chemical Corporation
InventorsRobert E. Booth, Francis E. Evans, Richard E. Eibeck, Martin A. Robinson
Estimating the term…
When saturated with boron trifluoride, certain polyhydric alcohols form adducts which catalyze hydrocarbon alkyl transfer reactions for which boron trifluoride is catalytic. The adduct is recovered from the reaction mixture and recycled, greatly reducing boron and fluoride values in the product and in any effluent. Examples include propylation of toluene in the presence of a recycled adduct of boron trifluoride with mannitol or sorbitol, and the oligomerization of decene by a recycled adduct of boron trifluoride with mannitol or butanediol. Some of the catalysts become viscous on cooling and are thus more easily separated from the reaction products which remain in a separate liquid phase.
In a method of reacting at least one unsaturated hydrocarbon in an alkyl transfer reaction of the type catalyzed by boron trifluoride, the improvement which comprises conducting the reaction in the presence of a catalytic amount of an adduct formed by saturating a butanediol with boron trifluoride and recovering the adduct from the reaction mixture and recycling the adduct.
Dependencies are inferred from the claim text.