Preparation of N-substituted oligo-imides
AssigneeRhone-Poulenc Industries
InventorsMichel Baudouin, Jean Abblard
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AssigneeRhone-Poulenc Industries
InventorsMichel Baudouin, Jean Abblard
Estimating the term…
N-substituted oligo-imides of the formula: ##STR1## in which D represents a divalent radical selected from the group comprising: ##STR2## in which m is 0 or 1, Y is hydrogen, chlorine or methyl, n is a positive integer of 5 or less, and R is an organic radical of valency n, containing up to 50 carbon atoms, are prepared by reacting an anhydride of the formula: ##STR3## with an amine of the formula: R--NH.sub.2).sub.n [III] in which formulae D, R, and n as above defined, said reaction being carried out in the presence of a catalyst system comprising a mixture of a compound (.alpha.) and a compound (.beta.), being a strong inorganic or organic oxygen-containing acid and (.beta.) being a salt of such acid with a cation selected from the group comprising pyridinium, quaternary phosphonium and tertiary sulfonium cations.
In a process for the preparation of an oligo-imide comprising reacting a dicarboxylic acid anhydride with an amine, the improvement which comprises conducting said reaction in the presence of a catalyst system comprising a mixture of a compound (.alpha.) and a compound (.beta.), (.alpha.) being a strong inorganic or organic oxygen-containing acid, said acid bearing at least one acid functionality having an ionization constant in water which is not greater than 3, and (.beta.) being a salt of such acid, with an organic cation selected from the group consisting of pyridinium nucleus cations, quaternary phosphonium cations and tertiary sulfonium cations.
Dependencies are inferred from the claim text.