Neutron absorbing article and method for manufacture of such article
AssigneeThe Carborundum Company
InventorsCarl H. McMurtry, Robert G. Naum, Dean P. Owens, Michael T. Hortman
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AssigneeThe Carborundum Company
InventorsCarl H. McMurtry, Robert G. Naum, Dean P. Owens, Michael T. Hortman
Estimating the term…
A neutron absorbing article, preferably in long, thin, flat form, suitable for but not necessarily limited to use in storage racks for spent nuclear fuel at locations between volumes of such stored fuel, to absorb neutrons from said spent fuel and prevent uncontrolled nuclear reaction of the spent fuel material, is composed of finely divided boron carbide particles and a solid, irreversibly cured phenolic polymer, forming a continuous matrix about the boron carbide particles, in such proportions that at least 6% of B.sup.10 from the boron carbide content is present therein. The described articles withstand thermal cycling from repeated spent fuel insertions and removals, withstand radiation from said spent nuclear fuel over long periods of time without losing desirable neutron absorbing and physical properties, are sufficiently chemically inert to water so as to retain neutron absorbing properties if brought into contact with it, are not galvanically corrodible and are sufficiently flexible so as to withstand operational basis earthquake and safe shutdown earthquake seismic events, without loss of neutron absorbing capability and other desirable properties, when installed in storage racks for spent nuclear fuel. The disclosure also relates to a plurality of such neutron absorbing articles in a storage rack for spent nuclear fuel and to a method for the manufacture of the articles.
A neutron absorbing article which comprises boron carbide particles in which the boron carbide content is at least 90% by weight and which are substantially all of a size to pass through a No. 20 U.S. Sieve Series screen and a solid, irreversibly cured phenol aldehyde condensation polymer cured to a continuous matrix about the boron carbide particles, with the proportion of boron carbide in the article being such that it contains at least 6% by weight of B.sup.10 from the boron carbide content thereof.
A method of absorbing neutrons from nuclear material which comprises interposing between such material and its surroundings a neutron absorbing article of boron carbide particles and a solid irreversibly cured phenolic polymer matrix about said particles, with the proportion of boron carbide in the structure being such that it contains at least 6% of B.sup.10 from the boron carbide content thereof.
A neutron absorbing article which comprises boron carbide particles of a B.sub.2 O.sub.3 content no more than 2% and a solid, irreversible phenolic polymer cured to a continuous matrix about the boron carbide particles.
Dependencies are inferred from the claim text.