Phenylglyoxylonitrile-2-oxime-cyanomethyl ether as a crop safener
AssigneeCiba-Geigy Corporation
InventorHenry Martin
Life of this patent
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Abstract
The new compound phenylglyoxylonitrile-2-oxime-cyanomethylether of the formula ##STR1## and compositions containing it, are used as a safener (antidote) for selectively combatting weeds in culture crops, especially sorghum and rice, in order to protect these cultivated plants from being injured by strong herbicides such as chloroacetanilides and thiolcarbamates. The safener is preferably applied to the crop seeds prior to planting.
Claims9
A herbicidal composition comprising (1) a herbicidally effective amount of a chloroacetanilide compound of the formula ##STR8## wherein R.sub.1 is lower alkyl, lower alkoxy, lower alkoxyalkyl, fluorine or chlorine and
- R.sub.2, R.sub.4 and R.sub.5 independently of one another are hydrogen, lower alkyl, lower alkoxy, lower alkoxyalkyl or chlorine and
- R is 1,3-dioxolan-2-yl-alkyl, 1,3-dioxolan-5-yl-alkyl, 1,3-dioxan-2-yl-alkyl, furanylmethyl or tetrahydrofuranylmethyl and (2) phenylglyoxylonitrile-2-oxime-cyanomethyl ether in sufficient amount to prevent injury to crops treated with said herbicide composition.
A method for protecting sorghum and rice crops from injury arising from the action of a herbicidal chloroacetanilide of the formula ##STR9## wherein R.sub.1 is lower alkyl, lower alkoxy, lower alkoxyalkyl, fluorine or chlorine and
- R.sub.2, R.sub.4 and R.sub.5 independently of one another are hydrogen, lower alkyl, lower alkoxy, lower alkoxyalkyl or chlorine, and
- R is 1,3-dioxolan-2-yl-alkyl, 1,3-dioxolan-5-yl-alkyl, 1,3-dioxan-2-yl-alkyl, furanylmethyl or tetrahydrofuranylmethyl,
- said method comprising applying to the soil in the rows of sorghum or rice seed, prior to treatment with the herbicide, a crop-protecting amount of phenylglyoxylonitrile-2-oxime-cyanomethyl ether.
A method for protecting crops from injury caused by application of a herbicidal chloroacetanilide compound of the formula ##STR10## wherein R.sub.1 is lower alkyl, lower alkoxy, lower alkoxyalkyl, fluorine or chlorine and
- R.sub.2, R.sub.4 and R.sub.5 independently of one another are hydrogen, lower alkyl, lower alkoxy, lower alkoxyalkyl or chlorine, and
- R is 1,3-dioxolan-2-yl-alkyl, 1,3-dioxolan-5-yl-alkyl, 1,3-dioxan-2-yl-alkyl, furanylmethyl, or tetrahydrofuranylmethyl,
- said method comprising applying to the crop seeds, a crop-protecting amount of phenylglyoxylonitrile-2-oxime-cyanomethyl ether.
A method for selectively controlling weeds in sorghum cultures which comprises applying to a culture of sorghum grown from seeds treated with a safening amount of phenylglyoxylonitrile-2-oxime-cyanomethyl ether, a herbicidally effective amount of a chloroacetanilide compound of the formula ##STR11## wherein R.sub.1 is lower alkyl, lower alkoxy, lower alkoxyalkyl, fluorine or chlorine, and
- R.sub.2, R.sub.4 and R.sub.5 independently of one another are hydrogen, lower alkyl, lower alkoxy, lower alkoxyalkyl, or chlorine, and
- R is 1,3-dioxolan-2-yl-alkyl, 1,3-dioxolan-5-yl-alkyl, 1,3-dioxan-2-yl-alkyl, furanylmethyl, or tetrahydrofuranylmethyl.
Rice or sorghum seed, the plants grown from which are resistant to injury be pre-emergence application of a herbicidal compound of the formula ##STR12## wherein R.sub.1 is lower alkyl, lower alkoxy, lower alkoxyalkyl, fluorine or chlorine, and
- R.sub.2, R.sub.4 and R.sub.5 independently of one another are hydrogen, lower alkyl, lower alkoxy, lower alkoxyalkyl, or chlorine, and
- R is 1,3-dioxolan-2-yl-alkyl, 1,3-dioxolan-5-yl-alkyl, 1,3-dioxan-2-yl-alkyl, furanylmethyl, or tetrahydrofuranylmethyl,
- said seed being coated with phenylglyoxylonitrile-2-oxime-cyanomethyl ether in an amount ranging from about 5 to about 500 grams per 100 kilograms of seed.
Dependencies are inferred from the claim text.