US 4,223,449 A · Heat-efficient method for dewatering solids

Abstract

Water is removed from a hydrocarbonaceous solid such as peat by contacting the solid with a liquid solvent relatively free of moisture such as benzene or toluene at elevated temperatures, i.e. 200.degree.-600.degree. F. and preferably at elevated pressures to prevent excessive volatilization, i.e. pressures of about 1 to about 100 atmospheres, to transfer at least a portion of the moisture in the solid to the solvent. The solvent is further characterized by its relative inability to dissolve appreciable amounts of water at low or ambient temperatures and its ability to dissolve substantially greater amounts of water at higher temperatures, i.e. 200.degree.-600.degree. F. After the solids are contacted with the solvent and while the solids and solvent are still at an elevated temperature, at least a portion of the solvent, now containing dissolved water, is removed from the solids to provide a product solids having a diminished water content. The removed liquid stream, containing solvent and water, is then cooled to a lower temperature, i.e. less than 150.degree. F., thereby causing the water to separate from the solvent as a separate phase and to provide a liquid solvent stream relatively free of moisture suitable for reuse in extraction of water from the solids. This system of moisture removal is particularly useful when a slurry of a solid in a solvent is to be prepared for passage to a high pressure reactor.

Claims17

Dependent claims

A process for treating a hydrocarbonaceous solid containing water to remove at least a portion of the water from the solid which comprises:

(i) contacting the water containing solid with a liquid solvent relatively free of moisture at an elevated temperature to transfer at least a portion of the water in the solid into the solvent, said solvent characterized by its ability to dissolve only relatively small amounts of water at low temperatures and its ability to dissolve substantially greater amounts of water at higher temperatures;
(ii) removing at least a portion of the solvent containing water from the resultant solids at an elevated temperature to provide a solvent stream containing water and a product solid stream having a diminished water content;
(iii) cooling the solvent containing water stream to a lower temperature to cause the water to separate from the solvent and to provide a liquid solvent stream relativey free of water and a water stream relatively free of solvent;
and,
(iv) passing at least a portion of the liquid solvent stream relatively free of moisture to contacting step (i) to provide at least a portion of the liquid solvent utilized therein.

2 more elements

In a process for the conversion of a water containing hydrocarbonaceous solid into a more valuable product in a conversion zone maintained at an elevated temperature and pressure wherein the present of water in the solid lowers the overall thermal efficiency of the conversion process, the improvement which comprises the removal of at least a portion of the water from the hydrocarbonaceous solid, said water removal comprising:

(i) contacting the water containing solid with a liquid hydrocarbon solvent relatively free of water at an elevated temperature to transfer at least a portion of the water in the solid into the solvent, said solvent characterized by its ability to dissolve relatively small amounts of water at low temperatures and its ability to dissolve substantially greater amounts of water at higher temperatures;
(ii) removing a portion of the solvent containing water from the resultant solids at an elevated temperature to provide a solvent stream containing water and a slurry of solids in admixture with at least a portion of the remaining solvent, said slurried solids having a diminished water content;
(iii) cooling the solvent stream containing water to a lower temperature to provide a liquid hydrocarbon solvent stream relativey free of water and a water stream relatively free of solvent;
(iv) passing at least a portion of the liquid hydrocarbon solvent stream relatively free of moisture to contacting step (i) to provide at least a portion of the liquid hydrocarbon solvent utilized therein;
and,
(v) passing the slurry of carbonaceous solids and solvent to the conversion zone for conversion to more valuable products whereby increased thermal efficiency is obtained.

3 more elements

Dependencies are inferred from the claim text.

Heat-efficient method for dewatering solids

Life of this patent

Heat-efficient method for dewatering solids

Life of this patent

Abstract

Claims17