High-temperature damping composite
AssigneeMinnesota Mining and Manufacturing Company
InventorsDonald B. Caldwell, Thomas F. Gardeski
Life of this patent
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Abstract
Vibration-damping composite comprising one or more structural metal sheets having adhered thereto a viscoelastic polycyanurate polymer which effectively damps vibrations at elevated temperatures after prolonged exposure thereto. A preferred structural sheet is dead-soft aluminum-killed steel.
Claims12
A composite at least 1/2 meter in both width and length of a structural metal sheet and a viscoelastic layer, which composite can be formed to provide components of or facings for machines in order to provide effective damping of vibrations in such machines during prolonged high-temperature operation,
- said metal sheet having an average plastic strain ratio r of at least 1.3, a strain-hardening exponent n of at least 0.11 in the equation
- .sigma.=K.epsilon..sup.n
- where .sigma. is the true stress, K is a constant and .epsilon. is the true strain, and a thickness of at least 0.2 mm, and
- said viscoelastic layer having a thickness of at least 20 micrometers and being a cured polycyanurate polymer comprising the repeating unit ##STR7## wherein each R is the residue after removal of the hydroxyl radicals from one of
- (a) HO--Ar--OH
- (b) ##STR8## (c) HOCH.sub.2 --(CH.sub.2 CH.sub.2).sub.j (CF.sub.2 CFX).sub.k ].sub.m CH.sub.2 OH
- (d) HO--CH.sub.2 CF.sub.2 (CF.sub.2).sub.h CF.sub.2 CH.sub.2 OH
- wherein
- h is 0 or an integer of 1 to 6,
- j and k are integers whose ratio j/k is 1/1 to 10/1,
- m is an integer of 1 to 100,
- n is an integer of 1 to 20,
- X is fluorine or perfluoroalkyl,
- --Ar--represents ##STR9## wherein Z represents --S--, --SO.sub.2 --, --O--, ##STR10## wherein R.sub.1 and R.sub.2 represent hydrogen, lower alkyl or ##STR11## wherein .omega. is an integer from 2 to 6, ##STR12## and the polycyanurate polymer has sufficient crosslinks such that its cyanurate nitrogen comprises 0.5 to 2% of its total weight when the polymer comprises 60% fluorine and 1.0 to 3.5% of its total weight when it is free from fluorine.
Dependencies are inferred from the claim text.