Polyamine/epihalohydrin reaction products

A process for the production of an acid stabilized resin solution which process comprises

• (A) polymerizing an aqueous solution of a diallylamine salt having the formula [(CH.sub.2 .dbd.C (R)--CH.sub.2).sub.2 NHR'.sym]sub.n X.sup. , wherein the R groups are the same or different and are selected from hydrogen and lower alkyl groups, R' is selected from hydrogen, alkyl and substituted alkyl groups, X.sup. is an anion selected from sulfate, bisulfate and nitrate in which the final pKa is less than 2 and n is an integer from 1 to 3 and is the valence of the anion;
• either alone or as a mixture with other copolymerizable monomers, selected from the group consisting of different diallylamines, monoethylenically unsaturated compounds containing a single vinylidene group and sulfur dioxide, in the presence of a free radical catalyst to form a polymer in which from 5 to 100% of the recurring units are derived from the diallylamine;
• (B) raising the pH of the solution sufficiently to convert part or all of the monomeric and polymeric amine salt functionalities to free amine groups but not so high as to precipitate the polyamine from solution;
• (C) reacting the polyamine with from about 0.5 to about 1.5 moles of an epihalohydrin per mole equivalent of secondary plus tertiary amine present in said solution, at a temperature of about 30.degree. to about 80.degree. C. and a pH from about 7 to about 9.5, to form a water-soluble resinous reaction product containing epoxide groups;
• and
• (D) reacting the resinous reaction product in aqueous solution, with from about 0.3 equivalents to about 1.2 equivalents per equivalent of epihalohydrin of a water-soluble acid selected from the group consisting of hydrogen halide acids, sulfuric acid, nitric acid, phosphoric acid, formic acid and acetic acid until an acid-stabilized resin solution is obtained.