Method for the removal of organic substances from alkali metal aluminate solution
AssigneeSumitomo Aluminum Smelting Company, Ltd.
InventorsJun-ichi Inao, Koichi Yamada, Takuo Harato, Hisakatsu Kato
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AssigneeSumitomo Aluminum Smelting Company, Ltd.
InventorsJun-ichi Inao, Koichi Yamada, Takuo Harato, Hisakatsu Kato
Estimating the term…
In the production of alumina from bauxite by the Bayer process, the present invention provides an improvement for effectively and economically removing organic substances from a circulating alkali aluminate solution by contacting the aluminate solution containing organic substances with molecular oxygen gas or a molecular oxygen-containing gas in the presence of copper ions as a catalyst at an elevated temperature, thereby oxidizing the organic substances, adding a chemical substance to the resulting aluminate solution which reacts with copper ions to deposit a water-insoluble precipitate, and separating the precipitate from the solution, and recycling the precipitate as a copper source to the above-mentioned wet oxidation procedure.
A method for removing organic substances from an alkali aluminate solution in the production of alumina from alumina-containing ores by the Bayer process or improved processes thereof, characterized by contacting the alkali aluminate solution containing organic substances with molecular oxygen gas or a molecular oxygen-containing gas of at least an amount corresponding to an oxygen amount necessary for oxidizing a required amount of organic substances contained in said aluminate solution under a pressure of 20 to 150 kg/cm.sup.2 and under such conditions that at least a pair of said aluminate solution is maintained in a liquid state and at a temperature of 180.degree. to 300.degree. C. in the presence of at least 100 mg/l, based on the amount of said aluminate solution of copper ions, thereby oxidizing the organic substances, adding to the resultant aluminate solution a chemical substance, which reacts with the copper ions to form a water-insoluble precipitate, precipitating the water-insoluble precipitate and separating the produced preciptate from the aluminate solution, and recycling the separated precipitate as a copper source to the above oxidation step.
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